Copper Alloy Plate Surface Finish for Soldering

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Solution Overview

Problem

Existing Co-Si based copper alloys face issues with incomplete removal of oxide films and foreign matter, leading to pinholes during soldering, which degrades solder wettability and increases imperfections in soldered areas, especially when acid pickling and grinding are not adequately performed before final rolling.

Innovation Solution

Conducting multiple rounds of acid pickling with a fine-textured buff after final heat treatment to ensure complete oxide film and foreign matter removal, achieving a smooth surface with specific anisotropy and reduced pinholes, while maintaining excellent solder wettability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If acid pickling and grinding are conducted before final rolling, then oxide film removal is improved, but pin holes are generated during soldering

Engineering Contradiction:
Improveoxide film removal completenessVSAvoidsoldering quality
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies preliminary action by conducting acid pickling and buffing with fine-textured grinding grains BEFORE final rolling to remove oxide films and foreign matters. This preliminary surface treatment ensures that when final rolling occurs, the surface is already clean and smooth, preventing pin hole formation during subsequent soldering processes.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the parameter of surface roughness by specifying Ra ≤ 0.2 μm and Rt ≤ 2 μm after the acid pickling and buffing process. This parameter control ensures the surface is smooth enough to prevent pin holes while maintaining adequate oxide film removal, resolving the contradiction between complete oxide removal and preventing soldering defects.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If buffing with acid pickling is conducted insufficiently, then productivity is improved, but solder wettability is degraded

Engineering Contradiction:
Improveprocessing efficiencyVSAvoidsolder wettability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the parameter of surface roughness to Ra ≤ 0.2 μm and Rt ≤ 2 μm, which provides optimal solder wettability. By controlling these parameters through buffing with fine-textured grinding grains, the patent achieves good soldering quality without requiring excessive processing steps, thus maintaining productivity while improving reliability.

Inventive Principle:
Principle #35Parameter changes

3Shape

If oxide film is not completely removed, then surface smoothness is maintained, but pin holes are generated during soldering

Engineering Contradiction:
Improvesurface smoothnessVSAvoidsoldering quality
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent simultaneously controls surface roughness parameters (Ra ≤ 0.2 μm, Rt ≤ 2 μm) and oxide film removal completeness through the acid pickling and buffing process. This dual parameter control ensures the surface is both smooth and free of oxide films that would cause pin holes, resolving the contradiction between maintaining surface smoothness and ensuring soldering quality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process significantly reduces pinholes and enhances solder wettability by ensuring a smooth surface with controlled surface roughness and specular gloss differences, improving the overall quality of soldered joints.

Implementation Method 1

acid pickling is conducted after a final heat treatment, and the oxide film is dissolved and further removed

Methodology Applied
Scientific EffectAcid pickling: Chemical Bonding

Implementation Method 2

buffing with acid pickling for a sufficient number of times using a relatively fine textured buff (grinding grains) after the final heat treatment such that the oxide film on the surface of the material and the foreign matters pushed by the rolling are removed

Methodology Applied
Scientific EffectAbrasion: Abrasion

Data Source

PatentEP2679341B1COPPER ALLOY PLATE COMPRISING Co AND Si
Publication Date: 2016.07.27 JX NIPPON MINING & METALS CORP
  • EP2679341B1 patent drawingFigure 1(a)~2
  • EP2679341B1 patent drawingFigure 3

AI summary

A Co-Si based copper alloy plate, comprising: Co: 0.5 to 3.0% by mass, Si: 0.1 to 1.0% by mass and the balance Cu with inevitable impurities, wherein the Co-Si based copper alloy plate satisfies the relationship {(60 degree specular gloss G(RD) in a rolling direction) - (60 degree specular gloss G(TD) in a direction transverse to rolling direction)} => 90%.