Copper Augmented Biochar for Chromium Removal

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Solution Overview

Problem

Current methods are inadequate for efficiently removing chromium from wastewater, which poses environmental and health risks due to its carcinogenicity and bioaccumulation potential.

Innovation Solution

A method involving the use of copper augmented biochar, prepared by pyrolyzing wheat straw and adding copper, is employed to contact with wastewater, achieving high chromium removal efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional methods are used to remove chromium from wastewater, then the process is simpler, but the removal efficiency is insufficient

Engineering Contradiction:
Improvechromium removal efficiencyVSAvoidcomplexity of removal method
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses copper-augmented biochar, which is a composite material combining biochar (derived from pyrolyzed agricultural waste) with copper nanoparticles or copper compounds. This composite structure synergistically enhances the chromium removal capacity beyond what either material could achieve alone, directly resolving the contradiction by improving removal efficiency through material composition rather than process complexity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The biochar component provides a porous structure with high surface area and numerous active sites for chromium adsorption. The porosity is developed through controlled pyrolysis of biomass, creating a network of micropores and mesopores that increase the contact area between the adsorbent and chromium ions in wastewater, thereby enhancing removal efficiency without requiring complex equipment

Inventive Principle:
Principle #31Porous materials

2Object-affected harmful factors

If chromium removal is not efficient, then the process is faster, but environmental and health hazards remain

Engineering Contradiction:
Improveenvironmental and health hazardsVSAvoidchromium removal efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent replaces complex mechanical or chemical treatment systems with a passive adsorption-based approach using copper-augmented biochar. The removal mechanism relies on natural adsorption phenomena (physisorption and chemisorption) rather than energy-intensive mechanical processes, achieving high chromium removal efficiency (90-99%) while minimizing operational complexity and environmental impact

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The biochar is prepared from inexpensive agricultural waste materials through simple pyrolysis, creating a low-cost adsorbent that can be easily discarded after use. This disposable approach eliminates the need for complex regeneration systems while maintaining high removal efficiency, directly addressing the hazard reduction goal without productivity compromise

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The copper augmented biochar effectively removes chromium from wastewater with up to 99% efficiency within 1 hour, significantly reducing environmental and health hazards.

Implementation Method 1

contacting the copper augmented biochar with the wastewater to remove chromium from the wastewater

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

pyrolyzing wheat straw to provide a biochar

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Data Source

PatentUS11866349B1Method of chromium (CR<sup>+6</sup>) removal from wastewater using copper augmented biochar
Publication Date: 2024.01.09 KING FAISAL UNIV
  • US11866349B1 patent drawing

AI summary

A method of chromium removal from wastewater comprising providing a copper augmented biochar and contacting the copper augmented biochar with the wastewater to remove chromium from the wastewater. The copper augmented biochar can remove chromium from wastewater with about 99% efficiency in about 1 hour.