Copper Ball Alpha Dose Reduction via Purity Control

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Solution Overview

Problem

Conventional Cu ball manufacturing processes do not adequately reduce alpha radiation, leading to software errors in high-density semiconductor mounting structures, and result in Cu balls with low sphericity that affect mounting performance.

Innovation Solution

Cu balls with a purity of 99.995% or less, containing impurities like Pb and Bi at 50 ppm or more, are manufactured using a specific heating process to limit alpha dose to 0.0200 cph/cm² or less, ensuring high sphericity and preventing software errors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If high purity Cu material is used to reduce alpha radiation, then alpha dose is decreased, but manufacturing cost increases

Engineering Contradiction:
Improvealpha doseVSAvoidmanufacturing cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The invention changes the purity parameter of Cu material from conventional high purity (99.99% or higher) to a specific range (99.97% to 99.99%), and adjusts impurity composition parameters (Pb: 0.003-0.01%, Bi: 0.003-0.01%, U: 0.005 ppb or less, Th: 0.005 ppb or less) to simultaneously achieve low alpha dose and cost-effectiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention selectively controls specific impurity elements (Pb, Bi, U, Th) while allowing other impurities to remain within acceptable ranges, optimizing the balance between alpha radiation reduction and manufacturing cost by targeting only the most critical elements

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If high purity Cu material is used, then alpha dose is decreased, but sphericity of Cu ball deteriorates

Engineering Contradiction:
Improvealpha doseVSAvoidsphericity
Core Design Contradiction:
Object-affected harmful factorsVSShape

Solution Approach 1:

The invention optimizes the purity parameter to a specific range (99.97%-99.99%) rather than maximizing it, and controls specific impurity levels to achieve the optimal balance between alpha dose reduction and maintaining high sphericity (98% or more)

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention accepts certain levels of non-critical impurities that are inexpensive to tolerate, focusing purification efforts only on elements that significantly impact both alpha radiation and sphericity

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of manufacture

If conventional Cu ball manufacturing process is used, then production cost is reduced, but alpha radiation increases causing software errors

Engineering Contradiction:
Improvemanufacturing costVSAvoidalpha radiation
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention modifies the manufacturing process parameters including purity control (99.97%-99.99%), specific impurity limits (Pb: 0.003-0.01%, Bi: 0.003-0.01%, U: 0.005 ppb or less, Th: 0.005 ppb or less), and heating temperature (100-300°C for 1-48 hours) to reduce alpha radiation while maintaining cost-effectiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention performs preliminary purification and impurity control during the Cu ball manufacturing process itself, rather than requiring post-manufacturing treatment, thereby reducing alpha radiation levels before the balls are used in semiconductor assemblies

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces alpha radiation-induced software errors and enhances sphericity, maintaining the structural integrity and performance of Cu balls in high-density mounting applications.

Implementation Method 1

α ray radiates by α decay of a radioactive isotope such as U, Th and 210

Methodology Applied
Scientific EffectAlpha decay: Radioactive Decay

Implementation Method 2

a Cu ball manufacturing process comprises: melting Cu material

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP2929960B1Copper ball
Publication Date: 2017.11.29 SENJU METAL IND CO LTD
  • EP2929960B1 patent drawingFigure 1~2
  • EP2929960B1 patent drawingFigure 3

AI summary

To provide Cu ball that has less α dose and high sphericity even when containing at least a certain amount of impurity elements other than Cu. Even when the purity thereof is 99.995% or less and U and Th contents are 5 ppb or less in order to suppress any software errors and decrease connection failure, α dose is 0.0200 cph/cm2 or less. Further, the sphericity of the Cu ball is unexpectedly improved by making the purity not more than 99.995%.