Copper-Ceramic Composite for Power Electronics Thermal Stress

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Solution Overview

Problem

Copper-ceramic composites used in power electronics face challenges with mechanical strength, thermal shock resistance, and bond wire detachment due to differences in thermal expansion coefficients between ceramic substrates and metal coatings, leading to potential detachment and crack formation under temperature fluctuations.

Innovation Solution

A copper-ceramic composite with a ceramic substrate containing aluminum oxide grains that have a maximum grain diameter and a shape factor of at least 0.4, optimized grain size distribution, and reinforcement with zirconium oxide, enhancing mechanical strength, thermal conductivity, and adhesive properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the metal coating is firmly bonded to the ceramic substrate, then the bond strength is improved, but thermal expansion stress increases during temperature fluctuations

Engineering Contradiction:
Improvebond strengthVSAvoidthermal expansion stress
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The metal coating is divided into multiple layers (first metal layer, second metal layer) with different properties. The first layer provides strong bonding to ceramic, while the second layer provides thermal expansion compensation, thus segmenting the functional requirements to resolve the contradiction between bond strength and thermal stress resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite metal coating structure combining different metal layers with complementary properties. This composite approach allows simultaneous achievement of strong ceramic bonding and thermal expansion stress resistance, resolving the contradiction between these two requirements.

Inventive Principle:
Principle #40Composite materials

2Strength

If the ceramic substrate has high mechanical strength, then crack resistance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvemechanical strengthVSAvoidmanufacturing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention optimizes specific parameters of the ceramic substrate (alumina grain size between 2-8 μm, specific grain boundary characteristics) to achieve high mechanical strength. By controlling these parameters within defined ranges, the substrate gains superior crack resistance without requiring complex manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

3Strength

If the aluminum oxide grain size is reduced, then mechanical strength is improved, but thermal conductivity decreases

Engineering Contradiction:
Improvemechanical strengthVSAvoidthermal conductivity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention identifies an optimal parameter range for alumina grain size (2-8 μm) that balances mechanical strength and thermal conductivity. This specific grain size range prevents excessive grain boundary resistance to heat flow while maintaining sufficient mechanical strength, resolving the contradiction between these two properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The ceramic substrate is formulated as a composite material with specific alumina grain structure and controlled grain boundary characteristics. This composite approach allows simultaneous optimization of mechanical strength and thermal conductivity through careful control of microstructural parameters.

Inventive Principle:
Principle #40Composite materials

4Reliability

If peripheral weakenings are added to reduce stress, then thermal shock resistance is improved, but mechanical strength decreases

Engineering Contradiction:
Improvethermal shock resistanceVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The metal coating is segmented into multiple functional layers, where the first layer provides stress relief through controlled structuring (peripheral weakenings, recesses), while the second layer maintains overall mechanical strength. This segmentation allows simultaneous achievement of thermal shock resistance and mechanical strength.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized composite exhibits improved flexural fracture strength, increased thermal shock resistance, and enhanced copper adhesive strength, reducing the risk of detachment and crack formation, thus providing a more reliable and durable solution for power electronics applications.

Implementation Method 1

the ceramic substrate contains aluminum oxide grains that have a maximum grain diameter and a shape factor of at least 0.4, optimized grain size distribution, and reinforcement with zirconium oxide, enhancing mechanical strength, thermal conductivity

Methodology Applied
Scientific EffectThermal conductivity: Conduction (thermal)

Implementation Method 2

Due to the different coefficients of thermal expansion of the ceramic substrate and of the metal coating, considerable mechanical stresses arise at the transition between these layers in the event of temperature fluctuations

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 3

The oxidation of copper foils before metallization of the ceramic substrate or introduction of oxygen during the high-temperature process forms a thin eutectic melt layer. This reacts with the surface of the ceramic substrate, so that ceramic and metal can be bonded firmly to one another

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

The DCB process exploits the fact that oxygen reduces the melting point of copper of 1083° C. to the eutectic melting point of 1065° C.

Methodology Applied
Scientific EffectEutectic reaction: Melting

Data Source

PatentUS11584696B2Copper-ceramic composite
Publication Date: 2023.02.21 HERAEUS ELECTRONICS GMBH & CO KG
  • US11584696B2 patent drawing
  • US11584696B2 patent drawing
  • US11584696B2 patent drawing

AI summary

A copper-ceramic composite: includes a ceramic substrate containing alumina and a copper or copper alloy coating on the ceramic substrate. The alumina has a mean grain shape factor Ra(Al2O3), defined as the arithmetic mean of the shape factors R of the alumina grains, of at least 0.4.