Copper Cobalt Ferrite Composition for Rare-Earth-Free Magnetostriction

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Solution Overview

Problem

There is a demand for rare-earth-free materials with high magnetostrictive properties due to the supply risks and poor mechanical properties of rare earth-based materials, limiting their industrial application.

Innovation Solution

Development of copper cobalt ferrites with a cubic crystal as the primary crystalline phase, which can be partially substituted with other elements, offering high magnetostrictive properties without rare earths.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If rare earth-based materials are used to achieve high magnetostrictive properties, then magnetostriction constant is improved, but supply reliability deteriorates and mechanical properties worsen

Engineering Contradiction:
Improvemagnetostrictive propertiesVSAvoidsupply reliability and mechanical properties
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The invention changes the chemical composition parameters by replacing rare earth elements with copper and cobalt in a spinel ferrite structure. Specifically, it uses the formula CuxCoyFe3-x-yO4 where x and y are controlled within specific ranges (0 < x ≤ 0.5, 0 < y ≤ 0.5, x + y ≥ 0.8), achieving high magnetostriction without rare earth elements. This parameter substitution resolves the contradiction between magnetostrictive performance and supply reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system combining copper, cobalt, and iron in a spinel ferrite structure. This composite approach (CuxCoyFe3-x-yO4) integrates multiple elements to achieve synergistic effects: copper and cobalt provide high magnetostriction while iron maintains structural stability, resolving the contradiction between performance and mechanical properties.

Inventive Principle:
Principle #40Composite materials

2Reliability

If rare earth-based materials are used to achieve high magnetostrictive properties, then magnetostriction constant is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvemagnetostrictive propertiesVSAvoidindustrial application restrictions
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention simplifies manufacturing by changing the material composition to common elements (copper, cobalt, iron) that are easier to source and process than rare earth elements. The spinel ferrite structure with controlled Cu and Co content provides a manufacturable alternative that reduces industrial application restrictions while maintaining high magnetostriction.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If copper cobalt ferrite with cubic phase is used to achieve high magnetostrictive properties, then magnetostriction constant is improved, but material composition complexity increases

Engineering Contradiction:
Improvemagnetostrictive propertiesVSAvoidmaterial composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention manages composition complexity by establishing clear parameter ranges: CuxCoyFe3-x-yO4 where 0 < x ≤ 0.5, 0 < y ≤ 0.5, and x + y ≥ 0.8. These defined parameters provide a systematic approach to composition control, balancing magnetostrictive performance with manageable material complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies local quality by optimizing specific element concentrations (Cu and Co content) within the spinel structure to achieve high magnetostriction. By controlling the distribution and concentration of copper and cobalt in specific ranges, it achieves localized optimization of magnetic properties without requiring complex overall composition.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The copper cobalt ferrites exhibit excellent magnetostrictive properties, suitable for applications in transducers, actuators, sensors, and vibration-powered generators, overcoming the limitations of rare earth-based materials.

Implementation Method 1

Magnetostrictive materials change their length when a magnetic field is applied without contact, which is called a 'magnetostriction effect' (Joule effect)

Methodology Applied
Scientific EffectMagnetostriction effect: Magnetostriction

Implementation Method 2

magnetostrictive materials undergo a change in magnetization when compressed and exhibit a change in magnetic permeability, which is called an 'inverse magnetostriction effect' (Villari effect)

Methodology Applied
Scientific EffectInverse magnetostriction effect: Villari Effect

Data Source

PatentUS20250212692A1Magnetostrictive material and element containing same
Publication Date: 2025.06.26 OSAKA UNIVERSITY
  • US20250212692A1 patent drawing
  • US20250212692A1 patent drawing
  • US20250212692A1 patent drawing

AI summary

Provided is a novel magnetostrictive material that has a high level of magnetostrictive properties without containing rare-earth elements. The magnetostrictive material contains a copper cobalt ferrite that contains a cubic crystal as a primary crystalline phase.