Copper Hair Dye Formulation with Nonionic Surfactants

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Solution Overview

Problem

Current oxidative hair dye formulations for achieving copper shades lack optimal color intensity, brilliance, and wash fastness, particularly shifting towards brown tones due to the presence of anionic surfactants.

Innovation Solution

A multicomponent packaging unit for oxidatively dyeing keratin fibers, comprising 1-(2-hydroxyethyl)-4,5-diamino pyrazole, 2,6-dihydroxy-3,4-dimethylpyridine, and hydrogen peroxide, with a minimal content of nonionic surfactants and no more than 0.6 wt% anionic surfactants, to produce intense and reddish copper shades with improved fastness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If anionic surfactants are used in oxidative hair dye formulations, then the formulation provides good foaming and emulsification properties, but the color intensity and brilliance of copper shades deteriorates with unwanted brown tones

Engineering Contradiction:
Improvefoaming and emulsification propertiesVSAvoidcolor intensity and shade accuracy
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent removes anionic surfactants from the formulation entirely and replaces them with nonionic surfactants. This extraction of the harmful component (anionic surfactants that cause brown tones) while retaining the necessary functional properties through alternative materials (nonionic surfactants) resolves the contradiction between ease of operation and manufacturing precision.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical parameter of the surfactant from anionic to nonionic type. This parameter change fundamentally alters the interaction with the dye components, preventing the formation of brown tones while maintaining foaming and emulsification properties, thus resolving the contradiction between operational ease and color precision.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If conventional oxidative dye formulations are used, then the color application is easy, but the wash fastness and durability of copper shades deteriorates

Engineering Contradiction:
Improvecolor application easeVSAvoidwash fastness and color durability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent extracts and removes anionic surfactants that interfere with color fastness, replacing them with nonionic surfactants that provide improved reliability. This removal of the harmful component eliminates the mechanism that causes color fading and browning during washing, while maintaining application ease.

Inventive Principle:
Principle #2Taking out (Extraction)

3Stability of the object's composition

If anionic surfactants are present in the formulation, then the formulation provides good stability, but the brilliance and reddish tone of copper shades deteriorates

Engineering Contradiction:
Improveformulation stabilityVSAvoidbrilliance and shade tone accuracy
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent changes the ionic parameter of the surfactant from anionic to nonionic, which fundamentally alters the chemical environment. This parameter change prevents the interaction between anionic surfactants and copper-containing dye components that causes browning, thereby maintaining both formulation stability and color brilliance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves brilliant, fashionable copper shades with enhanced color richness and wash fastness by minimizing anionic surfactant content, preventing the unwanted shift towards brown tones and ensuring long-lasting results.

Implementation Method 1

oxidative color-changing agents... oxidation dyes are used. Such coloring agents customarily include oxidation dye precursors, so-called developer components and coupler components, which form the actual dyes with one another under the influence of oxidizing agents

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

one or more nonionic surfactants... total content of all anionic surfactants (E) included in the agent is below 0.6 wt %

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS10034822B2Fashionable copper shades in a nonionic base
Publication Date: 2018.07.31 HENKEL KGAA
  • US10034822B2 patent drawing
  • US10034822B2 patent drawing
  • US10034822B2 patent drawing

AI summary

An agent for oxidatively dyeing keratinous fibers, in particular human hair, includes —in a cosmetic carrier—(A) 1-(2-hydroxyethyl)-4,5-diamino pyrazole and/or a physiologically acceptable salt thereof,(B) 2,6-dihydroxy-3,4-dimethylpyridine,(C) hydrogen peroxide, and(D) one or more nonionic surfactants,wherein the total content of all anionic surfactants (E) included in the agent is below 0.6 wt %, based on the total weight of the agent.A second subject matter of the present invention is a corresponding multicomponent packaging unit (kit-of-parts).