Copper Glass Biocidal Compositions Synergistic Efficacy

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Solution Overview

Problem

Current biocidal materials face challenges in achieving effective microbe inhibition across a wide range of organisms while maintaining stability and cost-effectiveness, as high concentrations of metals like copper are costly and may have undesirable effects, and organic biocides can be prohibitively expensive.

Innovation Solution

A biocidal material comprising copper-containing glass particles and organic co-biocides such as isothiazolinones, bicyclic oxazolidines, and bromine nitrogen-based compounds, which exhibit a synergistic effect, reducing the minimum bactericidal concentration and allowing for lower usage rates, thus enhancing efficacy and cost-effectiveness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentrations of metals like copper are used to achieve desired biocidal efficacy, then biocidal activity is improved, but cost increases and undesirable effects on coating composition occur

Engineering Contradiction:
Improvebiocidal efficacyVSAvoidcost and undesirable effects on coating composition
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent combines copper-containing glass particles with organic co-biocides (isothiazolinones, bicyclic oxazolidines, or bromine nitrogen-based compounds) to create a synergistic biocidal system. This merging allows achieving enhanced biocidal efficacy at lower individual concentrations, reducing both cost and harmful effects while maintaining reliability against diverse microorganisms

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses composite biocidal materials consisting of copper-containing glass particles combined with organic biocidal compounds. This composite approach leverages the complementary mechanisms of inorganic copper and organic biocides to achieve broader spectrum activity and improved efficacy at reduced concentrations, addressing the contradiction between effectiveness and cost/harmful effects

Inventive Principle:
Principle #40Composite materials

2Reliability

If high concentrations of organic biocides are used to achieve desired biocidal efficacy, then biocidal activity is improved, but cost increases

Engineering Contradiction:
Improvebiocidal efficacyVSAvoidcost
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent merges copper-containing glass particles with organic co-biocides to create a synergistic system where the combination is more effective than either component alone. This allows reducing the concentration and cost of expensive organic biocides while maintaining or improving biocidal efficacy through the complementary action of copper particles

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Copper-containing glass particles act as an intermediary that enhances the biocidal activity of organic compounds. The copper particles serve as a cost-effective base that amplifies the effect of smaller amounts of organic biocides, thereby reducing overall cost while maintaining high efficacy

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If a single biocide is used to simplify formulation, then ease of manufacture is improved, but biocidal spectrum and efficacy are limited

Engineering Contradiction:
Improveformulation simplicityVSAvoidbiocidal spectrum and efficacy
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention employs composite biocidal materials combining copper-containing glass particles with organic co-biocides. This composite formulation achieves broader biocidal spectrum and enhanced efficacy against diverse microorganisms while maintaining reasonable formulation simplicity through the integration of two complementary components

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of copper-containing glass particles and organic co-biocides demonstrates a synergistic effect, achieving bactericidal activity at lower concentrations than either component alone, providing improved biocidal efficacy and stability while reducing costs.

Implementation Method 1

copper-containing glass particles... a minimum bactericidal concentration (MBC) of a combination of the at least one co-biocide and the plurality of copper-containing glass particles is less than an MBC of the at least one co-biocide in the absence of the plurality of copper-containing glass particles

Methodology Applied
Scientific EffectIon release:

Implementation Method 2

A biocidal material comprising copper-containing glass particles and organic co-biocides such as isothiazolinones, bicyclic oxazolidines, and bromine nitrogen-based compounds, which exhibit a synergistic effect, reducing the minimum bactericidal concentration and allowing for lower usage rates, thus enhancing efficacy and cost-effectiveness

Methodology Applied
Scientific EffectSynergistic effect:

Data Source

PatentUS20240148002A1Biocidal compositions containing copper and a co-biocide
Publication Date: 2024.05.09 CORNING INC
  • US20240148002A1 patent drawing
  • US20240148002A1 patent drawing
  • US20240148002A1 patent drawing

AI summary

A biocidal material includes a carrier, a plurality of copper-containing glass particles, and at least one co-biocide selected from isothiazolinones, bicyclic oxazolidines, and bromine nitrogen-based compounds. A minimum bactericidal concentration (MBC) of a combination of the at least one co-biocide and the plurality of copper-containing glass particles is less than an MBC of the at least one co-biocide in the absence of the plurality of copper-containing glass particles.