Copper Interconnect Residue Conversion for Leakage Reduction

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Solution Overview

Problem

As integrated circuit component sizes decrease, electromigration-induced failures become a concern due to metallic residue left behind during metal cap deposition in copper interconnects, leading to leakage currents and time-dependent dielectric breakdown.

Innovation Solution

A post-deposition treatment process converts metallic residue into insulating material using nitrogen-based, oxygen-based, or silane-based ambients, rendering it electrically inert and preventing conductive pathways between interconnects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a metallic cap is disposed on top of copper interconnects to improve electromigration resistance, then higher currents can flow through the conductor, but metallic residue is formed during deposition which creates leakage currents and dielectric breakdown

Engineering Contradiction:
Improveelectromigration resistanceVSAvoidmetallic residue causing leakage currents
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful metallic residue into a beneficial insulating material by exposing it to oxygen plasma or oxidizing chemicals. This transformation changes the residue from a conductive contaminant causing leakage currents into a non-conductive protective layer, thereby eliminating the harmful effect while retaining the electromigration protection benefits of the metallic cap

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical state of the metallic residue from metallic (conductive) to oxidized (insulating). By controlling the oxidation process through plasma treatment or chemical exposure, the electrical conductivity parameter of the residue is fundamentally altered, preventing leakage currents and dielectric breakdown

Inventive Principle:
Principle #35Parameter changes

2Productivity

If component sizes are decreased to increase integration density, then more circuits can be packed into the chip, but electromigration-induced failures become more frequent due to residue formation

Engineering Contradiction:
Improveintegration densityVSAvoidelectromigration-induced failure rate
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

By converting the residue into an insulating material, the patent eliminates the source of electromigration-induced failures. This allows continued scaling to higher integration densities without the penalty of increased failure rates from leakage currents and dielectric breakdown

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The oxidized residue creates an inert, non-conductive environment around the interconnects, preventing electrical breakdown and electromigration-related failures. This inert layer protects the underlying copper structure even as dimensions are reduced and current densities increase

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly reduces leakage currents and improves yield by mitigating failures related to shorting and time-dependent dielectric breakdown, maintaining reliability of copper interconnects without degrading performance.

Implementation Method 1

oxidation converts the metallic residue 42 into the insulating material 52

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

nitridation converts the metallic residue 42 into the insulating material 52

Methodology Applied
Scientific EffectNitridation: Nitriding

Implementation Method 3

silylation converts the metallic residue 42 into the insulating material 52

Methodology Applied
Scientific EffectSilylation: Chemical Bonding

Data Source

PatentUS9748169B1Treating copper interconnects
Publication Date: 2017.08.29 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US9748169B1 patent drawing
  • US9748169B1 patent drawing
  • US9748169B1 patent drawing

AI summary

Techniques relate to treating metallic interconnects of semiconductors. A metallic interconnect is formed in a layer. A metallic cap is disposed on top of the metallic interconnect. Any metallic residue, formed during the disposing of the metallic cap, is converted into insulating material.