Copper-Manganese Catalyst Composite for Harmful Gas Removal

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Solution Overview

Problem

Existing catalysts for removing carbon monoxide, nitrogen oxide, ozone, and volatile organic compounds at room temperature are either expensive or have reduced efficiency due to noble metal limitations and sensitivity to water, with high-tech requirements for nano-sized particle dispersion.

Innovation Solution

A composite composition comprising a copper-manganese catalyst hybridized with an inorganic layer compound, an inorganic filler, activated carbon, and a binder, optimized for high specific surface area and porosity, providing efficient gas removal at room temperature with reduced production costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If noble metal catalysts (Au, Pd, Pt) are used for carbon monoxide removal at room temperature, then catalytic efficiency and durability are improved, but cost increases significantly

Engineering Contradiction:
Improvecatalytic efficiencyVSAvoidcost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the chemical composition parameters by replacing noble metals with base metals (Cu, Mn, Co, Ni, Zn) in specific ratios. The catalyst uses CuO-MnO2 as the primary active component with optional additions of CoO, NiO, and ZnO to optimize catalytic activity at room temperature while eliminating dependence on expensive noble metals.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs inexpensive base metal oxides (CuO, MnO2, CoO, NiO, ZnO) that can be obtained from common salts like copper sulfate, manganese sulfate, cobalt sulfate, nickel sulfate, and zinc sulfate. These materials are readily available, low-cost alternatives to noble metals, making the catalyst economically viable for widespread application.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Quantity of substance

If Hopcalite (manganese oxide-copper oxide mixture) is used for carbon monoxide removal, then cost-effectiveness and CO removal efficiency are improved, but efficiency drastically decreases in the presence of water

Engineering Contradiction:
Improvecost-effectivenessVSAvoidefficiency in presence of water
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent creates a composite catalyst system combining CuO-MnO2 with additional metal oxides (CoO, NiO, ZnO) to form a multi-component material. This composite structure synergistically improves water resistance while maintaining CO removal efficiency, overcoming the limitation of conventional Hopcalite that loses activity in humid conditions.

Inventive Principle:
Principle #40Composite materials

3Reliability

If nano-sized metal particles (5 nm) are used for carbon monoxide oxidation, then catalytic activity at room temperature is improved, but preparation technology complexity and dispersion requirements increase

Engineering Contradiction:
Improvecatalytic activityVSAvoidpreparation technology
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs porous ceramic supports with controlled pore structures to disperse and stabilize the metal oxide catalyst particles. The porous structure provides high surface area for catalytic activity while naturally preventing particle aggregation, eliminating the need for complex nano-particle dispersion techniques and specialized preparation equipment.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite composition effectively removes carbon monoxide, nitrogen oxide, and volatile organic compounds at room temperature, offering high gas removal efficiency and cost-effectiveness compared to conventional noble metal catalysts, with optimized density and porosity for enhanced adsorption.

Implementation Method 1

Hopcalite, which is a mixture of manganese oxide, copper oxide and the like, useful as a catalyst used for removing carbon monoxide at room temperature

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

a composite composition for harmful gas removal containing a copper-manganese catalyst, which is capable of removing ambient and indoor pollutants

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10556224B2Composite composition for harmful gas removal containing copper-manganese catalyst
Publication Date: 2020.02.11 SEILFA
  • US10556224B2 patent drawing
  • US10556224B2 patent drawing
  • US10556224B2 patent drawing

AI summary

This invention relates to a composite composition for harmful gas removal containing a copper-manganese catalyst, which is capable of removing ambient and indoor pollutants, such as carbon monoxide and volatile organic compounds, the composite composition including a copper-manganese composite catalyst hybridized with an inorganic layer compound, an inorganic filler, activated carbon, and a binder.