Copper Phosphate Radiation-Absorbing Plastic

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Solution Overview

Problem

Conventional plastic packaging materials are susceptible to degradation from UV and IR radiation, leading to reduced shelf life of products, material brittleness, and potential health hazards, while existing absorber systems often compromise transparency or stability.

Innovation Solution

A radiation-absorbing plastic-based material incorporating finely divided copper phosphate compounds like copper hydroxide phosphate, which effectively absorbs UV and IR radiation without significantly impairing transparency, and promotes the decomposition of hydrogen peroxide, offering germ-inhibiting properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional absorber materials are incorporated into polymer material, then UV and IR radiation absorption is improved, but transparency in the visible range deteriorates

Engineering Contradiction:
ImproveUV and IR radiation absorptionVSAvoidtransparency in visible range
Core Design Contradiction:
Object-affected harmful factorsVSIllumination intensity

Solution Approach 1:

The patent changes the chemical composition parameters by using specific copper phosphate compounds (Cu3(PO4)2, CuHPO4, Cu2HPO4) with defined crystal structures and particle sizes (0.1-10 μm). These parameter changes enable the material to absorb UV and IR radiation while maintaining visible transparency, resolving the contradiction between radiation protection and optical clarity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by dispersing inorganic copper phosphate absorber particles within an organic polymer matrix. This composite structure combines the radiation-absorbing properties of the inorganic compounds with the transparency and processability of the polymer, achieving both UV/IR absorption and visible light transmission.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If inorganic absorber materials are used in high doses, then radiation absorption is improved, but material transparency deteriorates due to heavy coloration or clouding

Engineering Contradiction:
Improveradiation absorption efficiencyVSAvoidmaterial transparency
Core Design Contradiction:
Object-affected harmful factorsVSIllumination intensity

Solution Approach 1:

The patent optimizes the dosage parameter by incorporating the copper phosphate compounds at concentrations of 0.01-10% by weight based on the polymer weight. This controlled dosing, combined with specific particle size reduction (0.1-10 μm), achieves effective radiation absorption while minimizing coloration and clouding effects that would otherwise occur at higher doses.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by ensuring uniform dispersion of the absorber particles throughout the polymer matrix. This even distribution prevents localized concentration effects that would cause clouding or heavy coloration, while still achieving sufficient overall absorption of UV and IR radiation across the entire material.

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If organic absorber materials are used, then transparency is maintained, but thermal stability deteriorates due to decomposition during processing

Engineering Contradiction:
ImprovetransparencyVSAvoidthermal stability during processing
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent replaces long-lived but thermally unstable organic absorber molecules with inorganic copper phosphate compounds that are thermally stable but may have limited solubility in the polymer matrix. The inorganic particles maintain their structural integrity during high-temperature processing, eliminating decomposition issues while preserving transparency through proper particle size control.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent substitutes organic molecular absorbers with inorganic particulate absorbers. This substitution replaces the molecular-level absorption mechanism of organic compounds with the electronic band structure absorption of inorganic solids, achieving superior thermal stability during processing while maintaining optical transparency through controlled particle morphology and size.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Object-affected harmful factors

If absorber materials are incorporated into polymer material, then radiation protection is improved, but processability and material properties may deteriorate

Engineering Contradiction:
Improveradiation protectionVSAvoidprocessability and material properties
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent changes the physical parameters of the absorber material by using finely divided particles with sizes of 0.1-10 μm. This particle size reduction improves dispersion characteristics and rheological properties, ensuring that the copper phosphate compounds do not significantly impair the processability of the polymer during extrusion, injection molding, or other common plastic processing operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the particulate nature of the copper phosphate absorbers, creating a composite structure where the inorganic particles are dispersed within the polymer matrix. This structure allows for effective radiation absorption while maintaining the continuous polymer phase that provides good processability and mechanical properties.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material effectively absorbs UV and IR radiation, maintains transparency, accelerates hydrogen peroxide decomposition, and exhibits germ-inhibiting effects, enhancing the safety and longevity of packaged products while being thermally stable and non-toxic.

Implementation Method 1

the absorber material or mixture of absorber materials from phosphates, condensed phosphates, phosphonates, phosphites and mixed hydroxide-phosphate-oxoanions of Copper (Cu), tin (Sn), calcium (Ca) and/or iron (Fe) is selected and is finely divided, dispersed or dissolved in the polymer matrix

Methodology Applied
Scientific EffectUV radiation absorption: Absorption (EM radiation)

Implementation Method 2

The plastic-based materials according to the invention absorb UV radiation and/or IR radiation very well

Methodology Applied
Scientific EffectIR radiation absorption: Absorption (EM radiation)

Implementation Method 3

it has been shown that the compounds used according to the invention as absorption materials, in particular the copper compounds, especially copper hydroxide phosphate, have an accelerating or catalyzing effect on the decomposition or decomposition of peroxides, such as hydrogen peroxide

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

The discovered germ-inhibiting and/or germicidal effect of the plastic-based materials according to the invention with incorporated copper phosphate compounds according to the invention

Methodology Applied
Scientific EffectAntimicrobial effect:

Data Source

PatentEP2403903B1Radiation-absorbing material
Publication Date: 2013.12.11 CHEM FAB BUDENHEIM AG

AI summary

The invention relates to a radiation-absorbing, plastic-based material composed of a polymer matrix having an absorber material or mixture of absorber materials contained therein, wherein the absorber material or mixture of absorber materials is selected from among phosphates, condensed phosphates, phosphonates, phosphites, and mixed hydroxide/phosphate oxoanions of copper (Cu), tin (Sn), calcium (Ca), and/or iron (Fe) and is present in the polymer matrix in a finely distributed, dispersed, or dissolved manner.