Copper Phosphonate Optical Filter for Thin UV–IR Absorption

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Solution Overview

Problem

Existing optical filters for solid-state imaging sensors face challenges in achieving desired transmittance properties with thinner layers and simplified production processes, particularly in UV-IR absorption, and there is uncertainty about the transmittance properties of certain absorber materials.

Innovation Solution

An optical filter with a light-absorbing layer having a thickness of 120 μm or less, composed of copper phosphonate and an organic dye, achieving specific transmittance requirements and using a composition with controlled by-product concentration to enhance absorption performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If a light-absorbing layer is made thinner to reduce imaging apparatus size, then the size and thickness are reduced, but achieving desired transmittance properties becomes more difficult

Engineering Contradiction:
Improvethickness of optical filterVSAvoidtransmittance properties
Core Design Contradiction:
Volume of moving objectVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters of the light-absorbing layer by using copper phosphonate compounds with specific molecular structures and controlled concentrations. This allows achieving the desired transmittance properties (70-90% in visible range, <5% in NIR range) with a reduced layer thickness of 120 μm or less, resolving the contradiction between thinness and optical performance.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If conventional UV-IR absorbers are used, then infrared and ultraviolet light can be absorbed, but the production process becomes complex and productivity decreases

Engineering Contradiction:
Improveinfrared and ultraviolet light absorptionVSAvoidproduction process complexity
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent merges UV absorption, visible light transmission, and NIR absorption functions into a single light-absorbing layer using copper phosphonate compounds. This eliminates the need for separate UV-IR absorbing layers and infrared-absorbing glass substrates required by conventional methods, significantly simplifying the production process and improving productivity while maintaining effective broad-spectrum absorption.

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If multiple layers are used to achieve desired transmittance properties, then optical performance is improved, but device complexity increases

Engineering Contradiction:
Improvetransmittance propertiesVSAvoidnumber of layers
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The copper phosphonate-containing light-absorbing layer is designed to perform multiple functions simultaneously: UV absorption, visible light transmission, and NIR absorption. This multi-functional layer replaces multiple separate layers required by conventional approaches, reducing device complexity from multi-layer structures to a single effective layer while maintaining or improving transmittance properties.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optical filter achieves high visible light transmittance, effective near-infrared shielding, and simplified production, conforming to human visual sensitivity with improved light absorption performance.

Implementation Method 1

an optical filter including a light-absorbing layer including a light absorber... The transmittance properties of optical filters including a light-absorbing layer are unlikely to be dependent on the incident angle

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Data Source

PatentUS12392946B2Optical filter and light-absorbing composition
Publication Date: 2025.08.19 NIPPON SHEET GLASS CO LTD
  • US12392946B2 patent drawing
  • US12392946B2 patent drawing
  • US12392946B2 patent drawing

AI summary

An optical filter (1a) has a thickness of 120 μm or less and satisfies the following requirements (i), (ii), (iii), and (iv): (i) an average transmittance in a wavelength range of 450 nm to 600 nm is 74% or more; (ii) a maximum transmittance in a wavelength range of 750 nm to 1080 nm is 1% or less; (iii) an infrared cut-off wavelength being a wavelength which lies in a wavelength range of 550 nm to 700 nm and at which a spectral transmittance is 50% is in a range of 600 nm to 680 nm; and (iv) an ultraviolet cut-off wavelength being a wavelength which lies in a wavelength range of 350 nm to 500 nm and at which a spectral transmittance is 50% is in a range of 350 nm to 420 nm.