Copper Pillar Sidewall Protection via Conformal Passivation

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Solution Overview

Problem

Conventional semiconductor packaging methods face reliability issues due to solder wetting on copper pillar sidewalls, leading to void formation and non-uniform intermetallic compounds, which degrade the quality of bonded joints and reduce their reliability under stress tests.

Innovation Solution

A method involving the formation of a conformal passivation layer on copper pillar sidewalls using a nonwettable polymer, such as parylene, which is selectively etched to leave only the sidewalls covered, preventing solder wetting and ensuring uniform solder joints through an anisotropic etching process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If no passivation layer is formed on copper pillar sidewalls, then the manufacturing process is simple, but solder wetting occurs on sidewalls causing void formation and non-uniform intermetallic compounds

Engineering Contradiction:
Improvebonded joint reliabilityVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A conformal passivation layer is deposited on the copper pillar sidewalls before the soldering process to prevent solder wetting. This preliminary protective action ensures that when solder is applied, it only contacts the intended surfaces (top of the pillar and substrate pad) rather than wetting the sidewalls, thereby preventing void formation and ensuring uniform intermetallic compound formation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The conformal passivation layer acts as an intermediary barrier between the solder and the copper pillar sidewalls. This intermediate layer prevents direct contact between solder and copper sidewalls, eliminating the harmful wetting effect while allowing the soldering process to proceed normally on the intended surfaces.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If a conformal passivation layer is formed on copper pillar sidewalls, then solder wetting is prevented and joint uniformity improves, but the manufacturing process complexity increases

Engineering Contradiction:
Improvesolder joint uniformityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The conformal passivation layer is deposited in advance using standard semiconductor fabrication techniques (such as CVD or PVD) before soldering. This preliminary step ensures precise coverage of the sidewalls with uniform thickness, which directly controls the subsequent soldering process to produce uniform joints without requiring complex real-time adjustments during soldering.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If solder wetting occurs on copper pillar sidewalls, then the process is simple without passivation, but void formation degrades joint quality

Engineering Contradiction:
Improvebonded joint reliabilityVSAvoidmanufacturing simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The conformal passivation layer serves as a mediator that blocks solder from wetting the copper sidewalls. This intermediate barrier allows the manufacturing process to remain relatively simple while eliminating the harmful effect of sidewall wetting that causes void formation, thereby improving joint reliability without significantly complicating the overall manufacturing flow.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the reliability of copper pillar connections by preventing solder wetting on sidewalls, resulting in more reliable and durable bonded joints that perform better under temperature cycling and high-temperature storage conditions.

Implementation Method 1

forming a conformal passivation layer on at least the sidewall of the metal post

Methodology Applied
Scientific EffectNonwetting: Wetting

Implementation Method 2

Horizontal portions of the conformal passivation layer may be removed utilizing an anisotropic etch

Methodology Applied
Scientific EffectAnisotropic etching:

Data Source

PatentUS9875980B2Copper pillar sidewall protection
Publication Date: 2018.01.23 AMKOR TECH SINGAPORE HLDG PTE LTD
  • US9875980B2 patent drawing
  • US9875980B2 patent drawing
  • US9875980B2 patent drawing

AI summary

Methods for copper pillar protection may include forming a metal post over a contact on a semiconductor die, where the metal post comprises a sidewall. A metal cap may be formed on the metal post and may be wider than the width of the metal post. A solder bump may be formed on the metal cap, and a conformal passivation layer may be formed on at least the sidewall of the metal post. The metal cap may be rounded shaped or rectangular shaped in cross-section. The metal post and the metal cap may comprise copper. The metal cap may comprise a copper layer and a nickel layer. The seed metal layer may comprise one or more of titanium, tungsten, and copper. The conformal passivation layer may comprise a nonwettable polymer. Horizontal portions of the conformal passivation layer may be removed utilizing an anisotropic etch such as a plasma etch.