Copper Precoat Composition for Uniform OSP Coatings

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Solution Overview

Problem

Current organic solderability preservative (OSP) processes for copper circuitry in printed wiring boards do not consistently produce uniform and cosmetically appealing coatings, which can lead to issues with solderability and surface oxidation.

Innovation Solution

A pre-treatment composition of an aliphatic carboxylic acid and an amine, such as heptanoic acid with triethanolamine, is applied to copper surfaces before the OSP coating, enhancing the uniformity and appearance of the final protective layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional OSP process is used to protect copper circuitry, then the copper is protected from oxidation, but the coating uniformity and cosmetic appearance are insufficient

Engineering Contradiction:
Improveoxidation protectionVSAvoidcoating uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies a pre-coat treatment to the copper surface before the main OSP coating process. This preliminary action prepares the copper surface by removing oxides and contaminants, creating a clean substrate that enhances the uniformity and adhesion of the subsequent OSP coating, while the OSP itself provides the oxidation protection.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent divides the coating process into two distinct stages: a pre-coat step and a main OSP coating step. This segmentation allows each step to be optimized independently - the pre-coat for surface preparation and uniformity, and the OSP for oxidation protection - thereby resolving the contradiction between coating quality and protection effectiveness.

Inventive Principle:
Principle #1Segmentation

2Device complexity

If the copper surface is not pre-treated, then the process is simpler, but the adhesion of the OSP coating and solderability are reduced

Engineering Contradiction:
Improveprocess complexityVSAvoidsolderability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The pre-coat treatment is applied as a preliminary step before the main OSP coating. This preliminary action activates the copper surface and removes contaminants, ensuring better adhesion and solderability. The pre-coat composition is specifically designed to prepare the surface without requiring complex additional equipment or processes.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If a pre-coat composition is applied before OSP, then coating uniformity and appearance are improved, but the process complexity increases

Engineering Contradiction:
Improvecoating uniformityVSAvoidprocess steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent combines the pre-coat treatment and OSP coating into a integrated process sequence that can be performed in a single production line without requiring separate equipment. The pre-coat composition is designed to be compatible with standard OSP materials, allowing the two steps to be merged into a unified coating process that improves uniformity without significantly increasing complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The pre-coat composition serves multiple functions: it cleans the copper surface, removes oxides, prepares the substrate for OSP adhesion, and contributes to the final coating uniformity. This multi-functionality reduces the need for separate treatment steps, thereby improving coating quality without proportionally increasing process complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pre-treatment step improves the solderability and appearance of the OSP coating, resulting in a more effective protective layer that prevents oxidation and enhances the adhesion of tin solder alloys on copper surfaces.

Implementation Method 1

contacting one or more copper surfaces with a pretreatment composition comprising a solution of an aliphatic carboxylic acid and an additive selected from the group consisting of amines and ammonia

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

The substrate is treated with the OSP solution to form a protective layer on the copper metallurgy

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP1996666B1Precoat composition for organic solderability preservative
Publication Date: 2014.06.04 MACDERMID INC

AI summary

An improved method of enhancing the solderability of a copper surface comprising the steps of contacting one or more copper surfaces with a pretreatment composition comprising a dilute solution of an aliphatic carboxylic acid and an additive selected from the group consisting of amines and ammonia and thereafter contacting the one or more surfaces with an organic solderability preservative composition. The improved organic solderability preservative process of the invention forms a more uniform coating that has a better appearance and color.