Copper Quantum Dot Hole Transport Layer for QLED Stability

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Solution Overview

Problem

Current Quantum Dot Light Emitting Diodes (QLEDs) face instability and poor charge transport due to the use of organic hole transport layers, which are sensitive to oxygen and humidity and have lower hole transport rates compared to inorganic materials.

Innovation Solution

A quantum dot light emitting device is developed with a copper-based quantum dot as the hole transport layer, featuring a short-chain ligand on its surface, which improves electrical conductivity and carrier transport efficiency by substituting long-chain ligands, enhancing device performance and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If organic hole transport layers are used in QLEDs, then the device can be manufactured with current technology, but the device exhibits poor stability due to sensitivity to oxygen and humidity

Engineering Contradiction:
Improvedevice stabilityVSAvoidsensitivity to oxygen and humidity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material composition parameter of the hole transport layer from organic materials to copper-based inorganic quantum dots, fundamentally altering the chemical properties to achieve resistance against oxygen and humidity while maintaining manufacturing feasibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by combining copper-based quantum dots with short-chain ligands to form a hybrid material that exhibits both the stability of inorganic materials and the processability of organic materials

Inventive Principle:
Principle #40Composite materials

2Productivity

If organic hole transport layers are used in QLEDs, then the device structure can be maintained, but the hole transport rate is lower compared to inorganic materials

Engineering Contradiction:
Improvehole transport rateVSAvoidmaterial composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent changes the material class from organic to inorganic quantum dots, achieving higher hole transport rates while managing the complexity through solution-based processing methods that simplify fabrication

Inventive Principle:
Principle #35Parameter changes

3Productivity

If long-chain ligands are used on copper-based quantum dots, then the quantum dots are easier to synthesize and handle, but the electrical conductivity and carrier transport efficiency are reduced

Engineering Contradiction:
Improveelectrical conductivityVSAvoidsynthesis and handling ease
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent changes the ligand chain length parameter from long-chain to short-chain, optimizing the balance between electrical conductivity and ease of manufacture by reducing the insulating effect while maintaining colloidal stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material with short-chain ligands that bridges the gap between the ease of handling quantum dots with long-chain ligands and the high conductivity required for device performance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of copper-based quantum dots with short-chain ligands improves the electrical conductivity and carrier transport efficiency, leading to better performance and stability of QLEDs, while being environmentally friendly and cost-effective.

Implementation Method 1

The use of copper-based quantum dots with short-chain ligands improves the electrical conductivity and carrier transport efficiency

Methodology Applied
Scientific EffectElectrical conductivity: Conduction (electrical)

Implementation Method 2

a copper-based quantum dot with a short-chain ligand on a surface... improves carrier transport efficiency

Methodology Applied
Scientific EffectCarrier transport: Conduction (electrical)

Data Source

PatentUS11825676B2Quantum dot light emitting device and application
Publication Date: 2023.11.21 BOE TECHNOLOGY GROUP CO LTD
  • US11825676B2 patent drawing
  • US11825676B2 patent drawing
  • US11825676B2 patent drawing

AI summary

The present disclosure discloses a quantum dot light emitting device and application thereof. The quantum dot light emitting device includes: an anode and a cathode disposed oppositely, a quantum dot light emitting layer arranged between the anode and the cathode, and a hole transport layer arranged between the anode and the quantum dot light emitting layer, wherein a material of the hole transport layer is a copper-based quantum dot with a short-chain ligand on a surface.