Core-Sheath Filament for Precise Adhesive Deposition

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Solution Overview

Problem

Conventional adhesive transfer tapes require die-cutting, leading to waste and limitations in precise application, especially in complex geometries, and traditional hot-melt adhesives have challenges with viscosity and stability during 3D printing processes.

Innovation Solution

The development of core-sheath filaments with a non-tacky sheath and a hot-melt processable adhesive core, containing a blend of transition metal compounds, accelerators, and curable components, which can be post-cured on a substrate using a liquid activator, allowing for precise deposition and reduced waste in adhesive application.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional adhesive transfer tapes are used, then adhesive application is simple, but die-cutting waste is generated and precise application in complex geometries is limited

Engineering Contradiction:
Improveadhesive application precisionVSAvoiddie-cutting waste
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The adhesive is segmented into filament form that can be deposited layer by layer in complex geometries, eliminating the need for die-cutting entire adhesive sheets and reducing waste

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The adhesive application transitions from 2D sheet-based die-cutting to 3D filament-based extrusion, enabling precise deposition in complex geometries and reducing material waste

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Ease of manufacture

If traditional hot-melt adhesives are used, then processing is straightforward, but viscosity and stability issues occur during 3D printing

Engineering Contradiction:
Improveprocessing simplicityVSAvoidadhesive viscosity stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The adhesive composition parameters are modified by adding transition metal compounds and curable components, enabling stable viscosity during printing and controlled curing after deposition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive uses a composite formulation combining polymer matrix, transition metal compounds, accelerators, and curable components to achieve both printability and stability

Inventive Principle:
Principle #40Composite materials

3Productivity

If adhesive is applied without post-curing, then process is simple, but geometric stability and substrate compatibility are reduced

Engineering Contradiction:
Improveprocess speedVSAvoidgeometric stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The adhesive is pre-formulated with curable components and transition metal compounds that remain dormant during printing, then activated after deposition to achieve final geometric stability and substrate compatibility

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables precise and controlled adhesive application without die-cutting waste, with improved geometric stability and flexibility in substrate compatibility, facilitating intricate bonding patterns and reduced volatile organic compounds (VOCs) in 3D printing processes.

Implementation Method 1

a hot-melt processable adhesive core, wherein the hot-melt processable adhesive core comprises a blend of: a hot-melt processable adhesive; a transition metal compound; an accelerator; and a curable component

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

a curable component; and II) a primer for adhesion of the core-sheath filament to a substrate comprising: an oxidizing agent

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 3

a primer for adhesion of the core-sheath filament to a substrate comprising: an oxidizing agent

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

b) melting and mixing the core-sheath filament to form a molten composition

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS12023855B2Core-sheath filaments and methods of printing an adhesive
Publication Date: 2024.07.02 3M INNOVATIVE PROPERTIES CO
  • US12023855B2 patent drawing

AI summary

A core-sheath filament having a non-tacky sheath and a hot-melt processable adhesive core, the sheath exhibiting a melt flow index of less than 15 grams per 10 minutes, is provided. Methods of making the core-sheath filament and methods of using the core-sheath filament to print a hot-melt processable adhesive onto a primer-treated substrate surface to provide a structural bond are described.