Core-Shell Cathode Material Using Recycled Battery Leachate

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Solution Overview

Problem

The existing processes for recovering valuable metals from waste batteries are complex, costly, and environmentally damaging, and they result in impurities that reduce the performance of positive electrode active materials in lithium secondary batteries.

Innovation Solution

A positive electrode active material is manufactured using a core-shell structure, where the core part is represented by Chemical Formula 1 (Li(Nia1Mnb1Coc1)O2) and the shell part by Chemical Formula 2 (Li(Nia2Mnb2Coc2)MeyO2), with a concentration gradient of nickel, cobalt, and manganese, and utilizing a leaching solution from waste battery recycling without separate solvent extraction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If separate extractants are used to extract valuable metals from waste battery, then the valuable metals (nickel, cobalt, manganese) can be recovered, but the process steps become complicated, extraction cost increases, purity is reduced, and environmental damage occurs

Engineering Contradiction:
Improverecovery of valuable metalsVSAvoidprocess steps
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent combines multiple separate extraction processes into a single integrated wet process that directly converts waste battery materials into positive electrode active material precursors. Instead of sequentially extracting nickel, cobalt, and manganese using separate extractants, the invention uses a unified chemical treatment approach that simultaneously recovers all valuable metals and directly forms the precursor material, thereby simplifying the overall process flow and reducing the number of process steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The wet process described in the patent serves multiple functions simultaneously: it extracts valuable metals from waste batteries, purifies the leaching solution, and directly prepares the precursor material for positive electrode active material synthesis. This multi-functional approach eliminates the need for separate extraction and purification stages, reducing process complexity while maintaining effective metal recovery.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Quantity of substance

If separate extractants are used to extract valuable metals from waste battery, then the valuable metals can be recovered, but the extraction cost increases

Engineering Contradiction:
Improverecovery of valuable metalsVSAvoidextraction cost
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent combines multiple separate extraction processes into a single integrated wet process that directly converts waste battery materials into positive electrode active material precursors. Instead of sequentially extracting nickel, cobalt, and manganese using separate extractants, the invention uses a unified chemical treatment approach that simultaneously recovers all valuable metals and directly forms the precursor material, thereby simplifying the overall process flow and reducing the number of process steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The wet process is designed to utilize the leaching solution itself as both the extraction medium and the precursor for material synthesis. The process exploits the chemical properties of the leaching solution to directly form the positive electrode active material precursor, eliminating the need for additional expensive extractants and purification agents, thereby reducing extraction costs.

Inventive Principle:
Principle #25Self-service

3Quantity of substance

If separate extractants are used to extract valuable metals from waste battery, then the valuable metals can be recovered, but the purity is reduced

Engineering Contradiction:
Improverecovery of valuable metalsVSAvoidpurity
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent applies a selective extraction approach where the wet process specifically targets and extracts valuable metals (nickel, cobalt, manganese) from the waste battery matrix while leaving impurities behind. The chemical treatment is designed to dissolve and separate the target metals with high selectivity, ensuring that the resulting leaching solution contains high concentrations of valuable metals with minimal contamination from other battery components.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The wet process described in the patent serves multiple functions simultaneously: it extracts valuable metals from waste batteries, purifies the leaching solution, and directly prepares the precursor material for positive electrode active material synthesis. This multi-functional approach eliminates the need for separate extraction and purification stages, reducing process complexity while maintaining effective metal recovery.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Quantity of substance

If separate extractants are used to extract valuable metals from waste battery, then the valuable metals can be recovered, but environmental damage occurs

Engineering Contradiction:
Improverecovery of valuable metalsVSAvoidenvironmental damage
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent converts the potentially harmful leaching solution, which would normally require complex solvent extraction and disposal procedures, into a beneficial precursor material for synthesizing positive electrode active materials. By transforming the waste stream into a useful intermediate product, the process eliminates environmental hazards associated with toxic extractants and disposal requirements while maintaining effective metal recovery.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent implements a comprehensive recovery approach that extracts valuable metals from waste batteries and simultaneously recycles the leaching solution into a useful precursor. Instead of discarding the leaching solution as waste requiring environmentally hazardous disposal, the invention recycles it as the basis for synthesizing new active material, thereby eliminating environmental damage while maximizing resource utilization.

Inventive Principle:
Principle #34Discarding and recovering

5Ease of manufacture

If valuable metals are extracted from leaching solution to manufacture positive electrode active material precursor, then the positive electrode active material can be manufactured, but the performance is inferior to material made of pure metal in terms of capacity and life maintenance rate

Engineering Contradiction:
Improvemanufacturing processVSAvoidcapacity and life maintenance rate
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes the composition and parameters of the leaching solution to ensure that the resulting positive electrode active material achieves high performance. By carefully controlling the chemical conditions, metal ratios, and processing parameters of the wet process, the invention produces precursors that yield active materials with capacity and life maintenance rates comparable to those made from pure metals, despite the recycled origin of the materials.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent produces positive electrode active materials with a core-shell structure where the composition is optimized to balance performance and cost. The material incorporates metals recovered from waste batteries in a controlled composite structure that maintains electrochemical performance, achieving both ease of manufacture from recycled materials and high reliability in terms of capacity and life maintenance rate.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the manufacturing process, reduces costs, and minimizes environmental impact while achieving high capacity retention and stable life characteristics for the positive electrode active material, with an 80-cycle capacity retention rate of 94% or more.

Implementation Method 1

a leaching solution obtained through a wet process to a waste battery

Methodology Applied
Scientific EffectWet process leaching: Solvation

Implementation Method 2

charged and discharged by intercalation-deintercalation of lithium ions

Methodology Applied
Scientific EffectIntercalation: Absorption (physical)

Data Source

PatentUS20250128961A1Positive electrode active material for lithium secondary batteries, method of manufacturing the same, and lithium secondary battery including the same
Publication Date: 2025.04.24 HYUNDAI MOTOR CO LTD
  • US20250128961A1 patent drawing
  • US20250128961A1 patent drawing
  • US20250128961A1 patent drawing

AI summary

Disclosed is a positive electrode active material including a core part represented by Chemical Formula 1 below and a shell part represented by Chemical Formula 2 below, the shell part surrounding the core part.Li(Nia1Mnb1Coc1)O2  [Chemical Formula 1]Li(Nia2Mnb2Coc2)MeyO2  [Chemical Formula 2]In the Chemical Formula 1 and the Chemical Formula 2,a1+b1+c1=1,a2+b2+c2+y=1,a1>a2,Me is at least one metal selected from the group consisting of Na, Al, Fe, Cu, Zn, Mg, Ca, B, Zr, Nb, and a combination thereof, andy is a total of moles of the at least one metal selected for the Me.