Core-Shell Semiconductor Nanoparticles for Stable Energy Levels

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Solution Overview

Problem

Existing semiconductor nanoparticles lack control over energy levels, leading to instability and inefficiency in electronic devices due to environmental sensitivity and chemical bonding limitations.

Innovation Solution

The development of semiconductor nanoparticles with a core-shell structure, where the first element in the core forms a chemical bond with a second element in the shell, allowing for controlled energy levels by adjusting the interface characteristics between the core and shell, thereby stabilizing the energy levels and improving device efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If semiconductor nanoparticles are used in electronic devices, then they exhibit excellent color purity and high luminous efficiency, but their energy levels are unstable and environmentally sensitive

Engineering Contradiction:
Improveenergy level stabilityVSAvoidenvironmental sensitivity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs a core-shell structure where a semiconductor core is coated with a shell material to form a composite nanoparticle. This composite structure stabilizes the energy levels by protecting the core from environmental factors while maintaining the optoelectronic properties. The shell acts as a barrier that reduces environmental sensitivity without compromising the luminous efficiency and color purity of the semiconductor core.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent controls and stabilizes energy levels by adjusting compositional parameters of the core-shell structure, including the ratio of elements in the core and shell, thickness of the shell, and chemical bonding characteristics at the interface. By optimizing these parameters, the invention achieves stable conduction and valence band levels that are less sensitive to environmental variations while maintaining high luminous efficiency.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the energy level of semiconductor nanoparticles is controlled by adjusting core-shell interface characteristics, then precise control of conduction and valence band levels is achieved, but the structural complexity increases

Engineering Contradiction:
Improveenergy level control precisionVSAvoidcore-shell structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies local quality by creating a specific interface region between the core and shell where chemical bonding occurs. This localized bonding at the core-shell interface is what provides precise control over energy levels. Rather than modifying the entire structure uniformly, the invention focuses the control mechanism at the specific location of the interface, achieving precise energy level control without unnecessarily increasing overall structural complexity.

Inventive Principle:
Principle #3Local quality

3Reliability

If a core-shell structure with chemical bonding at the interface is formed, then energy levels are stabilized, but the manufacturing process becomes more complex

Engineering Contradiction:
Improveenergy level stabilityVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs preliminary action by pre-forming the core structure with specific surface characteristics before adding the shell material. The core is prepared in advance with controlled composition and surface properties that facilitate desired chemical bonding with the shell. This sequential approach, where the core is prepared first and then coated with the shell under controlled conditions, stabilizes energy levels through predetermined interface bonding while managing manufacturing complexity through staged processing.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables precise control of conduction and valence band levels, enhancing the stability and efficiency of semiconductor nanoparticles, reducing environmental sensitivity and improving the performance of electronic devices.

Implementation Method 1

the first element and the second element are chemically bonded to each other on the at least a portion of the surface of the core

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 2

Semiconductor nanoparticles may receive light (e.g., a first light wave) from an excitation source and thus enter an excited state, and thereafter emit energy (e.g., light or a second light wave) corresponding to an energy band gap of the semiconductor nanoparticles

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS11870001B2Semiconductor nanoparticles, electronic device including the same, and method for manufacturing semiconductor nanoparticles
Publication Date: 2024.01.09 SAMSUNG DISPLAY CO LTD
  • US11870001B2 patent drawing
  • US11870001B2 patent drawing
  • US11870001B2 patent drawing

AI summary

An electronic device includes a semiconductor nanoparticle, and a method of manufacturing the semiconductor nanoparticle is additionally provided. The semiconductor nanoparticle includes: a core including a first element; and a shell covering at least a portion of a surface of the core and including a second element and a third element, wherein the first element, the second element, and the third element are different from each other, and the first element and the second element are chemically bonded to each other on the at least a portion of the surface of the core.