Core-Shell Rare Earth Magnet Coercivity
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Solution Overview
Problem
Conventional R-T-B based sintered magnets require improved coercivity, especially at high temperatures, to prevent demagnetization, while minimizing the use of heavy rare earth elements for resource saving and cost reduction.
Innovation Solution
A rare earth-based permanent magnet with a core-shell structure in its main phase grains, where the core part contains a higher concentration of heavy rare earth elements and the shell part contains a higher concentration of light rare earth elements, enhancing coercivity through pinning effects and reduced lattice defects.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If heavy rare earth elements (Dy, Tb, Ho) are added to increase coercivity, then coercivity is improved, but resource consumption increases and cost increases
Solution Approach 1:
The patent applies local quality by creating a core-shell structure where the core region contains high concentration of heavy rare earth elements (Dy, Tb, or Ho) to provide strong pinning effect and high coercivity, while the shell region contains light rare earth elements (Nd, Pr) to maintain saturation magnetization. This spatial differentiation of element distribution allows the magnet to achieve high coercivity with minimal overall heavy rare earth content, directly resolving the contradiction between improving coercivity and reducing heavy rare earth consumption.
2Reliability
If heavy rare earth elements are added to improve coercivity at high temperature, then resistance to demagnetization is improved, but manufacturing cost increases
Solution Approach 1:
The patent employs parameter changes by precisely controlling the concentration gradients of rare earth elements within the core-shell structure. The core contains heavy rare earth elements at concentrations optimized for high-temperature coercivity, while the shell contains light rare earth elements at concentrations optimized for saturation magnetization. This parameter optimization allows the magnet to maintain reliability at high temperatures while minimizing the overall amount of expensive heavy rare earth elements required, thereby reducing manufacturing cost.
3Strength
If the concentration of heavy rare earth elements is increased to enhance coercivity, then magnetic performance is improved, but residual magnetic flux density decreases
Solution Approach 1:
The core-shell structure implements local quality by concentrating heavy rare earth elements in the core region where they provide strong pinning effects to enhance coercivity, while the shell region is composed of light rare earth elements that contribute to high saturation magnetization. This spatial separation ensures that the heavy rare earth elements do not uniformly distribute throughout the grain, preventing the overall reduction of residual magnetic flux density while still achieving high coercivity through localized pinning at the core-shell interface.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The core-shell structure significantly increases coercivity and maintains residual magnetic flux density, making the magnet suitable for high-temperature applications with reduced heavy rare earth element content.
Implementation Method 1
enhancing coercivity through pinning effects and reduced lattice defects
Implementation Method 2
enhancing coercivity through pinning effects and reduced lattice defects
Data Source
AI summary
A rare earth based permanent magnet formed by a sintered compact with an R-T-B based composition, wherein, R contains R1 and R2 as the necessity, R1 represents at least one rare earth element including Y and excluding Dy, Tb and Ho, and R2 represents at least one from the group made of Dy, Tb and Ho. Its main phase grains have a core-shell structure in which a core part and shell part coating the core part are contained. When the atom concentrations of R1 and R2 in the core part and the atom concentrations of R1 and R2 in the shell part are defined as αR1, αR2, βR1 and βR2, respectively, αR1<βR1, αR2>βR2, αR1<αR2 and βR2<βR1. Relative to all the main phase grains observed at the cross-section of the sintered compact, the ratio occupied by the main phase grain having the core-shell structure is 5% or more.