Meniscus-Confined Core-Shell Metal Deposition for Complex Microstructures

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Solution Overview

Problem

Current methods face challenges in forming complex copper core structures and regulating metal shell structures for magnetically controlled surface array units, and lack equipment for supplying specialized metal ion solutions, hindering the manufacturing of tiny metal components with conformally deposited nickel shells.

Innovation Solution

A meniscus-confined electrochemical deposition device and method utilizing a macroscopic and microscopic moving platform, copper core structural system, shell-layer structural system, probe adjustment unit, and central control unit to form heterogeneous metal core-shell microstructures through precise control of electrolyte delivery and electric fields, enabling multi-layer deposition of different metals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If meniscus-confined electrochemical deposition is used to form copper core structures, then high precision shaping is achieved, but the formation of complex copper core structures remains challenging

Engineering Contradiction:
Improveshaping precisionVSAvoidcomplex copper core structure formation capability
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The device is divided into two independent structural systems: a copper core structural system for forming the core and a shell-layer structural system for forming the shell. This segmentation allows each system to be optimized independently, enabling complex core structures to be formed first, followed by conformal shell deposition.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The probe adjustment unit provides dynamic positioning capabilities with multiple degrees of freedom, allowing the microfine glass tube to be precisely positioned and repositioned during the deposition process. This dynamic adjustment enables the formation of complex three-dimensional copper core structures while maintaining high shaping precision.

Inventive Principle:
Principle #15Dynamics

2Device complexity

If a single electrolyte delivery system is used, then device simplicity is maintained, but the ability to supply various specialized metal ion solutions is lacking

Engineering Contradiction:
Improvedevice simplicityVSAvoidmetal ion solution supply capability
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The electrolyte delivery system is designed with multi-functionality, where the probe adjustment unit and electrolyte reservoir can accommodate different metal ion solutions (copper, nickel, zinc, silver) through sequential replacement. This universal design enables the same hardware platform to perform multiple deposition functions without requiring separate dedicated systems for each metal.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

Multiple electrolyte reservoirs are prepared in advance with different metal ion solutions, and the system pre-configures the appropriate electrolyte before each deposition step. This preliminary preparation allows rapid switching between different metals while maintaining operational simplicity during the actual deposition process.

Inventive Principle:
Principle #10Preliminary action

3Device complexity

If conventional electrochemical deposition is used, then equipment simplicity is maintained, but the regulation of metal shell structures is difficult

Engineering Contradiction:
Improveequipment simplicityVSAvoidmetal shell structure regulation
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The system implements local quality control by independently regulating the electrolyte delivery parameters and electrical parameters specifically at the deposition interface. The probe adjustment unit enables precise local positioning, while the electrochemical deposition power supply provides independent control of deposition conditions, allowing fine regulation of shell structure without complicating the overall equipment design.

Inventive Principle:
Principle #3Local quality

4Device complexity

If multi-material deposition is attempted without dedicated equipment, then device complexity is avoided, but in-situ deposition of multiple materials is hindered

Engineering Contradiction:
Improveequipment complexityVSAvoidmulti-material deposition efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The system maintains continuous productive action through rapid electrolyte replacement and seamless transition between deposition modes. The probe adjustment unit continuously positions the probe, while the electrolyte delivery system continuously supplies appropriate metal ion solutions, enabling uninterrupted multi-material deposition without requiring complex reconfiguration or causing downtime.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the fabrication of complex metal core-shell structures with precise control over deposition, allowing for the manufacturing of tiny metal components with conformally deposited shells and flexible tuning of electrochemical deposition processes.

Implementation Method 1

the meniscus-confined electrochemical deposition method utilizes a microfine glass tube as a delivery channel for the electrolyte, forming a stable meniscus bridge with a cathode substrate

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

metal ions are converted into metal atoms under the influence of a two-electrode potentiometer, leading to the formation of metal microstructures

Methodology Applied
Scientific EffectElectrochemical deposition: Electrodeposition

Implementation Method 3

the shell-layer structural system may include an electrolytic cell, an electrochemical deposition power supply, and a plurality of reservoirs

Methodology Applied
Scientific EffectElectrochemical deposition: Electrodeposition

Data Source

PatentUS20250389042A1Meniscus-confined electrochemical deposition devices for heterogeneous metal core-shell microstructures and methods
Publication Date: 2025.12.25 CHANGCHUN UNIV OF SCI & TECH
  • US20250389042A1 patent drawing
  • US20250389042A1 patent drawing
  • US20250389042A1 patent drawing

AI summary

Embodiments of the present disclosure provide a meniscus-confined electrochemical deposition device for a heterogeneous metal core-shell microstructure and a method, including a copper core structural system and a shell-layer structural system. The copper core structural system is used for a formation of a copper core structure, a microfine glass tube in the copper core structural system is mounted on a probe adjustment unit, and the probe adjustment unit is mounted on a macroscopic moving platform, which may realize micro-scale multi-material metal electrochemical deposition micro additive manufacturing. The shell-layer structural system is used for a formation of a shell layer structure, and the shell-layer structural system includes a plurality of reservoirs, which may realize a multi-layer core-shell structure covered with different metals, and flexible tuning of an electrochemical deposition device may be realized by adding different electrolyte reservoir supply systems.