Core-Shell Toner for Pressure-Based Fixing Without Heating

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Solution Overview

Problem

Existing electrostatic image developing toners with addition polymerization or polycondensation resins require heating for fixing due to insufficient pressure yield behavior, leading to image defects and adhesion issues in electrophotographic processes.

Innovation Solution

The use of electrostatic image developing toners with a core-shell structure, where both the core and shell are non-crystalline resins with a glass transition temperature difference of 20°C or greater, and the shell contains acidic or basic polar groups, allowing for pressure-induced plasticization and fixing without heating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If heating is applied for fixing toner images, then fixing reliability is improved, but energy consumption increases and image defects may occur

Engineering Contradiction:
Improvefixing reliabilityVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention changes the physical parameters of the toner by controlling the glass transition temperature difference between core and shell resins to be 20°C or greater, with the shell resin having a lower Tg. This parameter change enables the toner to undergo pressure-induced plasticization at lower temperatures, allowing fixing without heating while maintaining reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the thermal fixing mechanism with a mechanical pressure-based fixing mechanism. By applying pressure to the toner image, the core-shell structure undergoes pressure-induced plasticization that enables bonding without thermal energy input, thus substituting heating with mechanical compression

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If heating is applied for fixing toner images, then fixing reliability is improved, but image defects are caused

Engineering Contradiction:
Improvefixing reliabilityVSAvoidimage defects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention modifies the toner's thermal parameters by creating a core-shell structure with a 20°C or greater glass transition temperature difference. This parameter modification allows the toner to achieve proper fixing characteristics through pressure alone, eliminating the harmful effects of heating such as image defects and adhesion issues

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional toners are used, then manufacturing is simple, but pressure yield behavior is insufficient

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidpressure yield behavior
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention uses composite materials by combining two different resins in a core-shell structure. The core resin provides structural stability while the shell resin with lower glass transition temperature provides pressure-responsive properties. This composite structure achieves superior pressure yield behavior while remaining manufacturable through conventional toner production processes

Inventive Principle:
Principle #40Composite materials

4Manufacturing precision

If toner particle size is reduced for high-definition images, then image quality is improved, but film formation on photoreceptors increases

Engineering Contradiction:
Improveimage definitionVSAvoidfilm formation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The invention changes the surface properties of small toner particles through the core-shell structure, where the shell resin with specific glass transition temperature and functional groups prevents excessive adhesion. This allows use of smaller particles for high-definition imaging while preventing the harmful film formation that would otherwise occur

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables reliable fixing at low temperatures, reduces toner consumption, and achieves high-definition images with improved storage stability and prevention of image defects, while allowing for smaller toner particle sizes and reduced formation of films on photoreceptors.

Implementation Method 1

both of a resin constituting a core of the core-shell structure and a resin constituting a shell of the core-shell structure are a non-crystalline resin, a glass transition temperature of the resin constituting the core and a grass transition temperature of the resin constituting the shell are different by about 20° C. or greater

Methodology Applied
Scientific EffectPressure-induced plasticization: Plasticity

Implementation Method 2

a glass transition temperature of the resin constituting the core and a grass transition temperature of the resin constituting the shell are different by about 20° C. or greater

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 3

forming an electrostatic latent image on a surface of a latent image carrier

Methodology Applied
Scientific EffectElectrostatic charging: Electrostatics

Implementation Method 4

transferring the toner image onto a surface of a target to obtain a transferred toner image

Methodology Applied
Scientific EffectElectrostatic transfer: Electrostatic Induction

Data Source

PatentUS8105744B2Image forming method and image forming apparatus
Publication Date: 2012.01.31 FUJIFILM BUSINESS INNOVATION CORP
  • US8105744B2 patent drawing
  • US8105744B2 patent drawing
  • US8105744B2 patent drawing

AI summary

An image forming method includes forming an electrostatic latent image on a surface of a latent image carrier; developing the electrostatic latent image with a developing agent including a toner to form a toner image; transferring the toner image onto a surface of a target to obtain a transferred toner image; and fixing the transferred toner image; wherein the toner includes a resin particle having a core-shell structure, both of a resin constituting the core and a resin constituting the shell are a non-crystalline resin, glass transition temperatures of the resin constituting the core and the resin constituting the shell are different by about 20° C. or greater, the resin constituting the shell includes an acidic polar group, a basic polar group, or an alcoholic hydroxy group, and the fixing of the transferred toner image is performed by applying a pressure on the transferred toner image without heating.