Corn Fiber Ethanol Production via Acid Enzyme Hydrolysis

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional ethanol production processes from corn starch cannot utilize non-starch sugar polymers like hemicellulose and cellulose present in corn fibers, leading to inefficiencies and increased costs due to high moisture content in whole stillage and low ethanol production efficiency.

Innovation Solution

A process involving acid soaking, mix acid and enzyme treatments is used to release fermentable C5 and C6 sugars from corn fiber wet cake, followed by co-fermentation with a recombinant yeast to convert these sugars into ethanol.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional starch to ethanol processes are used, then starch portion of the grain is converted to ethanol, but non-starch sugar polymers like hemicellulose and cellulose in corn fiber cannot be utilized

Engineering Contradiction:
Improveethanol production efficiencyVSAvoidutilization of non-starch sugar polymers
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The invention changes the chemical parameters of the corn fiber wet cake by applying acid pretreatment (sulfuric acid and phosphoric acid mixture at 70°C for 30 minutes) to hydrolyze non-starch sugar polymers into fermentable sugars. This parameter change enables the subsequent fermentation process to utilize C5 and C6 sugars that were previously inaccessible to conventional yeast strains, thereby improving ethanol production efficiency from the entire corn fiber content.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies preliminary acid soaking and enzyme treatment to the corn fiber wet cake before fermentation to break down complex non-starch sugar polymers into simple fermentable sugars. This preliminary action prepares the substrate by releasing C5 and C6 sugars from hemicellulose and cellulose, making them available for fermentation and thus improving overall ethanol yield from the corn fiber.

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If whole stillage is dehydrated for use as feedstock, then moisture content is reduced, but energy consumption increases significantly

Engineering Contradiction:
Improveusability of whole stillage as feedstockVSAvoidenergy consumption for dehydration
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The invention uses the corn fiber wet cake, which is a by-product of the ethanol distillation process, directly as feedstock without requiring energy-intensive dehydration. The wet cake naturally contains the necessary components (cellulose, hemicellulose, starch) and the process utilizes acid pretreatment and fermentation to convert these into ethanol, thereby eliminating the need for separate dehydration operations and reducing energy consumption while maintaining operational feasibility.

Inventive Principle:
Principle #25Self-service

3Productivity

If acid soaking and mix acid enzyme treatments are applied to corn fiber wet cake, then fermentable C5 and C6 sugars are released, but process complexity increases

Engineering Contradiction:
Improvesugar recovery efficiencyVSAvoidnumber of treatment steps
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention merges the acid pretreatment step with the enzyme hydrolysis step into a integrated process flow. The acid soaking (sulfuric acid and phosphoric acid mixture) is followed immediately by enzyme treatment without separate intermediate processing steps. This merging of treatment steps achieves efficient release of C5 and C6 sugars from corn fiber while minimizing the number of separate operations, thereby reducing process complexity despite the multiple chemical treatments involved.

Inventive Principle:
Principle #5Merging (Combining)

4Productivity

If recombinant yeast is used to convert C5 and C6 sugars to ethanol, then ethanol production from corn fiber is improved, but fermentation process complexity increases

Engineering Contradiction:
Improveethanol production from C5 and C6 sugarsVSAvoidfermentation process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention employs a recombinant yeast strain that possesses multi-functionality by being capable of fermenting both C5 sugars (xylose, arabinose from hemicellulose) and C6 sugars (glucose from cellulose and starch) simultaneously into ethanol. This universal yeast strain eliminates the need for separate fermentation processes for different sugar types, thereby improving overall ethanol production from corn fiber while maintaining a relatively simple single-step fermentation process without requiring multiple specialized yeast cultures or sequential fermentation operations.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process increases the efficiency of sugar recovery and ethanol production, reducing operational costs by utilizing the entire corn fiber content and improving the digestibility of the resulting animal feed.

Implementation Method 1

A process involving acid soaking, mix acid and enzyme treatments is used to release fermentable C5 and C6 sugars from corn fiber wet cake

Methodology Applied
Scientific EffectAcid hydrolysis: Hydrolysis

Implementation Method 2

followed by co-fermentation with a recombinant yeast to convert these sugars into ethanol

Methodology Applied
Scientific EffectFermentation: Fermentation

Data Source

PatentUS12291735B2Method for the production of ethanol from corn fibers
Publication Date: 2025.05.06 PRAJ IND LTD
  • US12291735B2 patent drawing
  • US12291735B2 patent drawing

AI summary

Method for the production of ethanol from corn fibers. Invention relates to a process for the preparation of ethanol from a corn fiber containing feedstock by using a set of process steps specifically identified for the treatment of the said feedstock. It particularly relates to the use of a soaking followed by mix acid and enzyme treatment that release fermentable C5 and C6 sugars from said feedstock. It further relates to using a recombinant yeast to convert both C5 and C6 sugars to ethanol.