Correlation Spectrometer Using Synthetic Spectra and Diffractive Masks

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional correlation spectrometers are large and unwieldy due to the need for multiple reference cells, making it impractical to detect a large number of chemical species, and suffer from limited dynamic range and high noise levels due to narrow absorption bands of target compounds.

Innovation Solution

A correlation spectrometer using species-specific masks and diffractive elements to provide spectral filtering, allowing for compact design and improved sensitivity and selectivity by using synthetic spectra and Hadamard or Eigen masks to filter and detect target compounds.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If multiple reference cells containing target compounds are used to achieve high selectivity and detect multiple chemical species, then the detection capability for multiple species is improved, but the device size becomes large and unwieldy

Engineering Contradiction:
Improvedetection capability for multiple speciesVSAvoiddevice size
Core Design Contradiction:
Adaptability or versatilityVSVolume of moving object

Solution Approach 1:

The patent replaces physical reference cells with synthetic reference spectra stored in memory. These synthetic spectra are computer-generated representations of target compound absorption patterns, allowing the system to simulate multiple reference compounds without requiring physical cells for each one. This copying approach enables detection of multiple chemical species while maintaining a compact device size.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The patent substitutes the mechanical/optical system of multiple physical reference cells with an electronic/computational system. Instead of using actual reference cells that require physical space and mechanical handling, the system uses digitally stored spectral data processed by a computer, replacing the mechanical complexity with electronic information processing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If the spectral range is limited to regions near important absorption bands using bandpass filters, then the signal-to-background ratio is improved, but the dynamic range of the detector is reduced

Engineering Contradiction:
Improvesignal-to-background ratioVSAvoiddetector dynamic range limitation
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent changes the approach from passive optical filtering to active computational spectral processing. Instead of relying on bandpass filters to limit the spectral range and improve signal-to-background ratio, the system uses digital signal processing techniques to enhance the correlation signal while maintaining access to the full spectral range, thereby preserving detector dynamic range.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a computer-based correlation processing system as an intermediary between the detector and the final measurement result. This computational intermediary performs spectral correlation analysis that can extract weak absorption signals from the full spectrum without requiring physical bandpass filtering, thus maintaining detector dynamic range while achieving high measurement precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the detection of multiple chemical species in a compact format with enhanced sensitivity and selectivity, reducing noise and improving the signal-to-background ratio by using synthetic spectra and species-specific masks.

Implementation Method 1

a diffraction grating, wherein the diffraction grating spectrally disperses the sample spectrum light

Methodology Applied
Scientific EffectDiffraction: Diffraction

Implementation Method 2

a mask wheel comprising a region of coded masks to provide spectral filtering of the sample spectrum light

Methodology Applied
Scientific EffectOptical filtering: Filter (optical)

Implementation Method 3

a broadband photodetector for recording the spectrally filtered sample spectrum light

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS7697134B1Correlation spectrometer
Publication Date: 2010.04.13 NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA LLC
  • US7697134B1 patent drawing
  • US7697134B1 patent drawing
  • US7697134B1 patent drawing

AI summary

A correlation spectrometer can detect a large number of gaseous compounds, or chemical species, with a species-specific mask wheel. In this mode, the spectrometer is optimized for the direct measurement of individual target compounds. Additionally, the spectrometer can measure the transmission spectrum from a given sample of gas. In this mode, infrared light is passed through a gas sample and the infrared transmission signature of the gasses present is recorded and measured using Hadamard encoding techniques. The spectrometer can detect the transmission or emission spectra in any system where multiple species are present in a generally known volume.