Cosmetic Hydroxyl Compound via Staged Esterification

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Solution Overview

Problem

Existing cosmetic ester compounds derived from reacting triglycerin with isostearic acid and dimer acid face challenges in achieving a homogeneous state and compatibility with oily bases, resulting in poor emollient, moisturizing properties, and affinity to the skin.

Innovation Solution

A hydroxyl compound is obtained by reacting diglycerin with isostearic acid and then with dimer acid, adjusting the molar ratios to achieve an appropriate hydroxyl value, viscosity, and molecular weight, ensuring compatibility and stability in cosmetics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If triglycerin is reacted with isostearic acid and dimer acid to form an ester compound, then the cosmetic can provide emollient and moisturizing properties, but the reaction produces highly viscous substances and polymers that prevent homogeneous mixing and reduce compatibility with oily bases

Engineering Contradiction:
Improveemollient and moisturizing propertiesVSAvoidhomogeneous state and compatibility
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent segments the esterification process into two distinct stages: first reacting triglycerin with isostearic acid to form triglycerin isostearate, then reacting this intermediate with dimer acid. This segmentation prevents the formation of highly viscous polymers that would occur in a single-step reaction, maintaining homogeneous mixing and compatibility with oily bases while still achieving the desired emollient and moisturizing properties.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs a preliminary esterification reaction between triglycerin and isostearic acid before introducing dimer acid. This preliminary action creates an intermediate product (triglycerin isostearate) with appropriate viscosity and reactivity, preventing the direct formation of high-molecular-weight polymers and ensuring homogeneous composition throughout the final cosmetic product.

Inventive Principle:
Principle #10Preliminary action

2Stability of the object's composition

If higher alcohols such as behenyl alcohol, stearyl alcohol, isostearyl alcohol, or phytosterol are used to create wax-type ester compounds with dimer acid, then the cosmetic can provide structural stability, but the affinity to skin becomes weak

Engineering Contradiction:
Improvestructural stabilityVSAvoidaffinity to skin
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent changes the key parameter from using higher alcohols (behenyl, stearyl, isostearyl alcohol, phytosterol) to using triglycerin as the alcohol component. This parameter change fundamentally alters the molecular structure and properties of the ester compound, enabling it to maintain structural stability through the dimer acid content while simultaneously improving skin affinity due to the triglycerin-based structure that better mimics natural skin lipids.

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If oligomeric esters with high molecular weight are produced from dimer acid reactions, then the cosmetic can provide viscosity and texture, but the reaction mixture becomes difficult to mix homogeneously and reproduce consistently

Engineering Contradiction:
Improveviscosity and textureVSAvoidhomogeneous state and reproducibility
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The patent segments the oligomerization process by controlling the reaction to form only mono- and di-ester intermediates in the first stage, rather than allowing uncontrolled formation of high-molecular-weight polymers. This segmentation of the molecular weight distribution ensures consistent viscosity and texture while maintaining homogeneous mixing and reproducible manufacturing results.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the molecular weight parameter by controlling the esterification degree through staged reactions and appropriate molar ratios. This produces an oligomeric ester with moderate molecular weight that provides sufficient viscosity and texture for cosmetic applications while avoiding the excessive polymerization that would compromise homogeneous mixing and manufacturing reproducibility.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting hydroxyl compound provides enhanced emollient and moisturizing properties, improved affinity to the skin, and storage stability, while reducing the need for plant waxes in cosmetic formulations.

Implementation Method 1

reacting diglycerin with isostearic acid

Methodology Applied
Scientific EffectEsterification: Chemical Bonding

Implementation Method 2

reacting the obtained ester compound with dimer acid

Methodology Applied
Scientific EffectEsterification: Chemical Bonding

Data Source

PatentUS9820932B2Cosmetic
Publication Date: 2017.11.21 KOKYU ALCOHOL KOGYO CO LTD

AI summary

The present invention relates to cosmetics comprising a hydroxyl compound obtained by the reaction of a di- or higher-valent alcohol with a monovalent carboxylic acid and dimer acid, characterized in that the hydroxyl compound is obtained by reacting diglycerin with isostearic acid, and then reacting the obtained ester compound with dimer acid, wherein a molar ratio among diglycerin, isostearic acid and dimer acid is in the range of 1.0:1.4 to 1.6:0.5 to 0.8. The present invention provides cosmetics comprising the hydroxyl compounds having a high hydroxyl value.