Liquid-Crystal Medium with Coumarin Acrylate for Flexible Displays

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Solution Overview

Problem

Current liquid crystal (LC) mixtures for flexible displays suffer from insufficient phase separation between polymer walls and LC molecules, leading to reduced transparency, contrast, and mechanical stability, along with issues like non-uniform pixel size and inadequate adhesion to substrates, due to the use of polymerisable compounds with absorption maxima at shorter UV wavelengths, which do not match the emission spectra of typical UV lamps.

Innovation Solution

A liquid crystal medium comprising polymerisable compounds with a coumarin group connected to an acrylate or methacrylate group, via a hydrocarbon spacer, which enhances photopolymerisation speed and mechanical strength, allowing for the formation of polymer walls with clear phase separation and improved adhesion, while shifting absorption to higher UV wavelengths for better compatibility with flexible substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If polymerisable compounds with absorption maxima at shorter UV wavelengths are used, then photopolymerisation can proceed, but the absorption does not match the emission spectra of typical UV lamps, reducing photopolymerisation efficiency

Engineering Contradiction:
Improvephotopolymerisation speedVSAvoidenergy matching between UV lamp emission and compound absorption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent changes the absorption wavelength parameter of the polymerisable compound by introducing a coumarin group, shifting it from shorter UV wavelengths to higher wavelengths that match the emission spectrum of typical UV lamps, thereby improving energy utilization and photopolymerisation efficiency

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional polymerisable compounds are used, then the LC mixture can be processed, but insufficient phase separation occurs between polymer walls and LC molecules, leading to reduced transparency and contrast

Engineering Contradiction:
Improvephase separation qualityVSAvoiddisplay transparency and contrast
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent introduces a coumarin group with specific optical properties that enhance the local optical characteristics of the polymer walls, improving light absorption and reducing light scattering, thereby enhancing display transparency and contrast

Inventive Principle:
Principle #3Local quality

3Strength

If polymer walls are formed to maintain gap distance, then structural support is provided, but mechanical strength and adhesion to substrates are insufficient

Engineering Contradiction:
Improvemechanical strength of polymer wallsVSAvoidadhesion to substrates
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a composite system combining the coumarin-containing polymerisable compound with the LC host mixture, where the coumarin group forms a crosslinked polymer network that provides both mechanical strength and improved adhesion to substrates through enhanced interfacial interactions

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed LC medium enables the formation of polymer walls with high mechanical strength, clear phase separation, and improved adhesion, resulting in enhanced display performance with higher transparency, contrast, and stability, suitable for flexible and unbreakable LC displays.

Implementation Method 1

The proposed LC medium enables the formation of polymer walls with high mechanical strength, clear phase separation, and improved adhesion, resulting in enhanced display performance with higher transparency, contrast, and stability

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentEP3802730B1Liquid-crystal medium
Publication Date: 2023.04.19 MERCK PATENT GMBH
  • EP3802730B1 patent drawingFigure 1(a)~2
  • EP3802730B1 patent drawingFigure 3
  • EP3802730B1 patent drawing

AI summary

The present invention relates to a liquid crystal (LC) medium comprising polymerisable compounds, to a process for its preparation, to its use for optical, electro-optical and electronic purposes, in particular in LC displays, and to LC displays comprising it.