Coupled Star Polymers for Tire Tread Durability and Traction

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Solution Overview

Problem

Current rubber compositions for vehicle tires lack optimal performance in terms of durability and traction, particularly in the tread component, due to limitations in the functionalization and coupling of polymers, which affect the tire's mechanical properties and wear resistance.

Innovation Solution

A process for producing coupled star polymers by polymerizing conjugated diene and vinyl aromatic monomers using an anionic initiator, followed by reaction with vinyl group-functionalized aminosilane compounds and further coupling with functionalizing compounds, resulting in polymers with multiple chains bonded to a functionalizing compound, enhancing the polymer's structural integrity and properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional rubber compositions are used for tire treads, then the basic tire function is maintained, but the durability and traction performance are insufficient

Engineering Contradiction:
ImprovedurabilityVSAvoidtraction performance
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent creates a composite polymer system by coupling multiple polymer chains to a central functionalizing compound core. This star polymer architecture combines different polymer chains (up to four) with a central core containing specific functional groups, creating a composite material that simultaneously achieves improved durability through enhanced structural integrity and better traction performance through optimized surface properties and interfacial adhesion.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent segments the polymer structure into distinct functional components: a central functionalizing compound core and multiple polymer chains radiating from it. This segmentation allows each component to contribute specific properties - the core provides structural integrity and durability, while the polymer chains provide traction and flexibility, resolving the contradiction between durability and traction performance.

Inventive Principle:
Principle #1Segmentation

2Strength

If polymer functionalization is increased to improve mechanical properties, then the processing complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvemechanical propertiesVSAvoidprocessing complexity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent incorporates functional groups directly into the polymer chain structure during the polymerization process itself, rather than requiring subsequent separate functionalization steps. This preliminary action of embedding functionality during manufacturing simplifies the overall production process while still achieving the desired mechanical properties enhancement.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the polymerization process with the functionalization process by using anionic initiators that incorporate functional groups directly into the polymer chains. This combining of processes eliminates separate functionalization steps, reducing manufacturing complexity while maintaining enhanced mechanical properties.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coupled star polymers improve the mechanical properties and wear resistance of tire components, specifically the tread, leading to enhanced durability and traction performance.

Implementation Method 1

polymerizing at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer using an anionic initiator to produce polymer chains with a living end

Methodology Applied
Scientific EffectAnionic polymerization: Chemical Bonding

Implementation Method 2

reacting the living end polymer chains from (a) with a vinyl group-functionalized aminosilane compound having formula I: (H2C=CH)-(A)a-Si(R1

Methodology Applied
Scientific EffectVinyl group functionalization: Chemical Bonding

Data Source

PatentEP3592789B1Coupled polymer products, methods of making and compositions containing
Publication Date: 2023.05.03 BRIDGESTONE CORP
  • EP3592789B1 patent drawing

AI summary

Disclosed herein is a coupled polymer product comprising polymer with up to four polymer chains bonded to a functionalizing compound of formula II, wherein the polymer chains are comprised of conjugated diene-containing monomers optionally in combination with vinyl aromatic monomers and further include vinyl group-functionalized silane compound of formula I bonded within the polymer chain. Also disclosed are processes for producing the coupled polymer product as well as a rubber composition containing the coupled polymer product and tire components comprising the rubber composition.