Cover Window Two-Step Etching for Fluoride-Free Glass Strength

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Solution Overview

Problem

The manufacturing of cover windows for flexible displays faces challenges in maintaining strength due to weight and thickness reduction, exacerbated by the formation of insoluble fluoride during etching with fluorine-based compounds, which hinders complete removal of micro-defects.

Innovation Solution

A two-step etching process using a fluorine-based acidic solution followed by a basic solution, accompanied by cleaning with acidic and basic solutions, effectively removes insoluble fluoride and micro-defects, enhancing the strength of the cover window.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If the cover window thickness is reduced to achieve weight reduction and flexibility, then the flexibility and weight are improved, but the strength and impact resistance are degraded

Engineering Contradiction:
Improveweight of cover windowVSAvoidstrength of cover window
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The patent applies parameter changes by modifying the surface properties of the glass through chemical etching processes. By controlling the etching depth and surface roughness parameters, the glass maintains sufficient strength even at reduced thickness, resolving the contradiction between weight reduction and strength maintenance.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the surface of the cover window is etched with a fluorine-based compound solution to remove micro-defects, then the surface quality is improved, but insoluble fluoride is generated on the glass surface which prevents complete etching

Engineering Contradiction:
Improvesurface quality of cover windowVSAvoidinsoluble fluoride on glass surface
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent segments the etching process into multiple sequential steps using different solutions. First, a fluorine-based compound removes micro-defects, then subsequent cleaning solutions remove the generated insoluble fluoride. This segmentation allows each step to address specific aspects of surface quality without leaving harmful residues.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent converts the harmful insoluble fluoride byproduct into a removable intermediate layer. The fluoride generation is anticipated and managed by introducing subsequent cleaning steps that specifically target and remove this byproduct, transforming a harmful effect into a controllable process intermediate.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Strength

If multiple etching and cleaning steps are added to improve surface quality and remove insoluble fluoride, then the surface quality and strength are improved, but the manufacturing process complexity increases

Engineering Contradiction:
Improvestrength of cover windowVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent merges multiple functions into integrated process steps. The etching and cleaning operations are combined in a sequential workflow where each solution serves both etching and cleaning functions simultaneously, reducing the need for separate dedicated steps and simplifying the overall manufacturing process.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method improves the impact resistance and strength of the cover window by reducing surface roughness and completely removing micro-defects, resulting in improved durability against external shocks.

Implementation Method 1

etching an entire surface of the panel glass with a first etching solution including a fluorine-based compound

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Implementation Method 2

etching the entire surface of the panel glass with a second etching solution different from the first etching solution

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS12471486B2Method of manufacturing cover window and method of manufacturing display apparatus including cover window
Publication Date: 2025.11.11 SAMSUNG DISPLAY CO LTD
  • US12471486B2 patent drawing
  • US12471486B2 patent drawing
  • US12471486B2 patent drawing

AI summary

A method of manufacturing a cover window includes: cutting mother glass into panel glass; chamfering the panel glass; etching an entire surface of the panel glass with a first etching solution including a fluorine-based compound; etching the entire surface of the panel glass with a second etching solution different from the first etching solution; and cleaning the panel glass with a basic cleaning solution.