CPP-Peptide Conjugates for Endothelial Apoptosis Inhibition

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Solution Overview

Problem

There is a need for pharmacological treatments that effectively target microvascular injury, which is characterized by endothelial cell apoptosis and leads to conditions such as microhemorrhages and no-reflow phenomena, particularly in cardiac and cerebral pathologies, with existing treatments failing to provide adequate vasculoprotection.

Innovation Solution

The use of conjugates comprising specific peptides, such as Tat-DAXXp and Tat-FADDp, which interact with the FAS receptor to inhibit endothelial cell apoptosis, thereby reducing vascular damage and promoting vasculoprotection in conditions like myocardial infarction and hemorrhagic stroke.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional treatments are used for microvascular injury, then general cardiovascular support is provided, but specific vasculoprotection against endothelial apoptosis is not achieved

Engineering Contradiction:
Improvevasculoprotection efficacyVSAvoidendothelial cell apoptosis
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs FADD and DAXX proteins as intermediary molecules that mediate between the FAS death receptor signal and the apoptotic machinery. These intermediaries block the transmission of apoptotic signals in endothelial cells, preventing cell death while maintaining normal physiological functions. This intermediary approach provides specific vasculoprotection without interfering with other cardiovascular treatments.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention extracts and isolates the specific apoptotic signaling pathway (FAS-FADD-DAXX) from the complex cascade of cellular responses to microvascular injury. By targeting only this specific pathway with selective inhibitors, the treatment prevents endothelial apoptosis without affecting other cellular processes, achieving precise vasculoprotection while avoiding off-target effects.

Inventive Principle:
Principle #2Taking out (Extraction)

2Object-affected harmful factors

If no specific anti-apoptotic therapy is applied, then treatment simplicity is maintained, but vascular damage and microhemorrhages worsen

Engineering Contradiction:
Improvevascular damageVSAvoidtreatment complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The FADD and DAXX proteins serve as specific intermediaries in the apoptotic pathway, providing a targeted therapeutic approach. By administering these intermediary molecules or their mimetics, the treatment specifically blocks vascular damage without requiring complex multi-component therapies, thus reducing treatment complexity while improving vascular protection efficacy.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the biochemical parameters of the apoptotic pathway by introducing exogenous FADD or DAXX proteins that alter the signaling dynamics. This parameter change approach transforms the irreversible apoptotic process into a protected state, reducing vascular damage through a single targeted intervention rather than multiple complex treatments.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If FAS-FADD dependent pathway is activated, then inflammatory response is induced, but endothelial cell death increases

Engineering Contradiction:
ImproveinflammationVSAvoidcell survival
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent applies partial action by selectively modulating the FAS-FADD-DAXX pathway at a specific point in the signaling cascade. By introducing FADD or DAXX proteins in controlled amounts, the treatment achieves sufficient blockade of the apoptotic signal to prevent cell death and reduce inflammation, without completely suppressing the pathway's physiological functions, thus maintaining cell survival while controlling harmful inflammatory responses.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The peptides demonstrate significant anti-apoptotic effects, reducing vascular complications and enhancing vascular density, thereby improving patient outcomes in conditions like myocardial infarction and hemorrhagic stroke.

Implementation Method 1

inhibitors of endothelial apoptosis for use in the treatment of a condition due to microvascular injury

Methodology Applied
Scientific EffectApoptosis inhibition:

Implementation Method 2

the FAS-FADD dependent pathway in vascular cells contributes to both caspase-dependent apoptosis and pro-inflammatory gene induction via NF-kB

Methodology Applied
Scientific EffectFAS-FADD-DAXX pathway interaction:

Data Source

PatentEP4691494A1Inhibitors of endothelial apoptosis for use in the treatment of a condition due to microvascular injury
Publication Date: 2026.02.11 CENT NAT DE LA RECH SCI (C N R S)
  • EP4691494A1 patent drawingFigure 1A~1C
  • EP4691494A1 patent drawingFigure 2A~2C
  • EP4691494A1 patent drawingFigure 3A~3C

AI summary

The invention relates to a conjugate comprising a peptide having the amino acid sequence set forth in SEQ ID NO: 1 or SEQ ID NO: 2, linked to a cell-penetrating peptide (CPP), for use in the treatment of a condition due to microvascular injury.