Crosslinkable Ester Urethane Resins Plastic Waste Recycling

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Solution Overview

Problem

The recycling of plastics, particularly polyethylene, polypropylene, PVC, and PET, is inefficient, resulting in only about 9% of all plastic ever produced being recycled, with the majority ending up in landfills or the environment, where they degrade into microplastics and release toxic additives.

Innovation Solution

Development of crosslinkable ester and urethane resins through compounds of specific formulas, which can participate in polymerization reactions, allowing for the recycling of polymers into high-value resins or prepolymers, and subsequent production of plastics with improved properties through crosslinking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional recycling methods (melting) are used, then recycling process is simple, but the physical and mechanical properties deteriorate due to oxidation and molecular weight reduction

Engineering Contradiction:
Improverecycling process simplicityVSAvoidphysical and mechanical properties
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the recycling process by using chemical reagents (compounds of formula I, II, III, IV, or V) to facilitate polymerization reactions, transforming the recycling mechanism from simple melting to chemical transformation, thereby improving material properties while maintaining process feasibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite resin compositions by combining recycled polymer with specific chemical compounds (formulas I-V) that contain functional groups capable of polymerization, resulting in materials with enhanced physical and mechanical properties compared to virgin plastics

Inventive Principle:
Principle #40Composite materials

2Reliability

If chemical recycling methods are used to produce high-value resins, then material properties improve, but the process complexity increases

Engineering Contradiction:
Improvematerial propertiesVSAvoidrecycling process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces chemical compounds (formulas I-V) as intermediaries that mediate between the recycled polymer and the desired resin product. These compounds contain functional groups that initiate polymerization reactions, simplifying the overall process by providing a clear chemical pathway from waste polymer to high-value resin

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies chemical parameters by introducing specific functional groups (carboxylic acid, ester, urethane) through compounds of formula I-V, enabling controlled polymerization reactions that transform recycled polymer into resin with tailored properties and standardized process parameters

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional recycling is used, then processing is straightforward, but environmental harm increases due to microplastic formation and toxic additive release

Engineering Contradiction:
Improveprocessing straightforwardnessVSAvoidmicroplastic formation and toxic additive release
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful waste polymer into beneficial resin material through controlled chemical transformation. By using compounds of formula I-V to initiate polymerization, the process transforms waste plastic into valuable resin products, eliminating microplastic formation and toxic additive release while maintaining processing feasibility

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical state of the polymer from waste form to resin form through controlled polymerization reactions using compounds of formula I-V, fundamentally altering the material's properties to eliminate harmful effects while maintaining ease of processing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution enables the effective recycling of plastics into high-quality resins and plastics, overcoming the limitations of traditional recycling methods by producing materials with superior properties compared to virgin plastics, while reducing environmental impact.

Implementation Method 1

wherein, for at least one of Q1 and Q2, at least one of R1 and R2 can participate in a polymerization reaction

Methodology Applied
Scientific EffectPolymerization reaction: Photopolymerisation

Implementation Method 2

a method of producing a plastic comprising crosslinking the compound of Formula I

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentUS20250154335A1Crosslinkable ester and urethane resins
Publication Date: 2025.05.15 UNIVERSITY OF ALABAMA
  • US20250154335A1 patent drawing
  • US20250154335A1 patent drawing
  • US20250154335A1 patent drawing

AI summary

Disclosed herein are crosslinkable ester and urethane resins and methods of making the same. Also disclosed are methods of recycling plastic waste by converting them to crosslinkable ester and urethane resins.