Crosslinked Lithium Battery Anode for Spring-Back Suppression
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Solution Overview
Problem
The spring back phenomenon during the manufacturing of secondary battery electrodes leads to increased thickness, affecting the volume of the final battery cell and potentially causing damage, which deteriorates the manufacturing processability.
Innovation Solution
Incorporating a thermal crosslinking additive in the anode mixture layer, with a binder weight greater than the additive weight, to enhance adhesion and alleviate stress, thereby suppressing the spring back phenomenon.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If the electrode thickness is reduced to secure high energy density, then the energy density is improved, but the spring back phenomenon occurs causing thickness increase and manufacturing difficulty
Solution Approach 1:
The patent applies preliminary action by incorporating a thermal crosslinking additive into the anode mixture layer before electrode formation. This additive undergoes thermal crosslinking during battery manufacturing processes (such as drying or forming), creating a crosslinked binder network that pre-establishes dimensional stability. This preliminary structural reinforcement prevents spring back phenomenon during subsequent manufacturing steps, enabling precise thickness control even when electrodes are manufactured at reduced thickness for high energy density applications.
2Volume of stationary object
If the electrode thickness is reduced to minimize cell volume, then the cell volume is reduced, but damage to the electrode occurs during manufacturing
Solution Approach 1:
The patent applies composite materials by creating a composite binder system consisting of a base binder and a thermal crosslinking additive. This composite formulation, where the additive crosslinks with the binder upon heating, generates a reinforced three-dimensional network structure within the anode mixture layer. This composite structure significantly enhances the mechanical strength and dimensional stability of thin electrodes, preventing damage during manufacturing processes while enabling minimized cell volume through reduced electrode thickness.
3Ease of manufacture
If conventional binders are used without thermal crosslinking additive, then the manufacturing process is simple, but electrode adhesion is insufficient and spring back occurs
Solution Approach 1:
The patent applies parameter changes by introducing a thermal crosslinking additive that undergoes chemical transformation when exposed to heat during standard battery manufacturing processes. This parameter change (thermal activation) triggers crosslinking reactions that significantly enhance electrode adhesion and structural stability. The approach maintains manufacturing simplicity because the crosslinking occurs passively during existing process steps (drying, forming, or initial charging), without requiring additional equipment or complex process modifications, yet achieves superior adhesion strength compared to conventional binders.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The use of a thermal crosslinking additive improves electrode adhesion, reduces electrode thickness variation, and enhances the energy density of the secondary battery by minimizing the need for additional rolling processes and preventing damage.
Implementation Method 1
thermal crosslinking additive included in the anode mixture layer
Data Source
AI summary
According to an embodiment, an anode for a secondary battery includes: an anode current collector; and an anode mixture layer on at least one surface of the anode current collector, wherein the anode mixture layer includes an anode active material, a binder, and a thermal crosslinking additive, and a weight of the binder included in the anode mixture layer is greater than a weight of the thermal crosslinking additive included in the anode mixture layer.According to an embodiment of the disclosed technology, energy density of the anode for a secondary battery may be improved.


