Crosslinked Cationic Polymer Fabric Conditioner Viscosity

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Solution Overview

Problem

Existing fabric conditioner polymers face challenges in achieving high viscosity while maintaining weight efficiency and preventing soil redeposition, which leads to undesirable blotchy appearances on fabrics.

Innovation Solution

A fabric conditioner composition using a crosslinked water swellable cationic polymer with less than 25% water soluble polymeric chains and a high level of cross-linking, specifically a copolymer of acrylamide and trimethylaminoethylmethacrylate chloride, is developed, improving weight efficiency and reducing soil redeposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If standard cationic polymeric thickeners are used to increase viscosity, then the viscosity of fabric conditioner is improved, but soil redeposition increases leading to blotchy appearance on fabrics

Engineering Contradiction:
ImproveviscosityVSAvoidsoil redeposition
Core Design Contradiction:
TemperatureVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the polymer by controlling the cross-linking degree (5-50 mmol per mole of cationic monomer units) and molecular weight (10,000-1,000,000 g/mol). This optimization allows the polymer to provide sufficient viscosity while reducing soil redeposition compared to standard thickeners

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses cross-linked cationic polymeric thickeners that combine multiple functional properties: viscosity building, soil anti-redeposition, and fabric softening. The cross-linked structure creates a composite material that simultaneously addresses viscosity requirements while preventing soil redeposition through its specific molecular architecture

Inventive Principle:
Principle #40Composite materials

2Temperature

If additional softening active is added to increase viscosity, then the viscosity of fabric conditioner is improved, but the cost significantly increases

Engineering Contradiction:
ImproveviscosityVSAvoidcost
Core Design Contradiction:
TemperatureVSQuantity of substance

Solution Approach 1:

The cross-linked cationic polymer serves multiple functions simultaneously: it acts as a thickening agent to increase viscosity, as an anti-redeposition agent to prevent soil redeposition, and as a fabric softener. This multi-functionality eliminates the need to add separate softening actives solely for viscosity control, thereby reducing overall formulation cost

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Temperature

If highly water soluble polymers are used to achieve high viscosity, then the viscosity of fabric conditioner is improved, but the polymer amount required increases reducing weight efficiency

Engineering Contradiction:
ImproveviscosityVSAvoidpolymer amount
Core Design Contradiction:
TemperatureVSQuantity of substance

Solution Approach 1:

The patent optimizes the water solubility parameter by controlling the cross-linking degree and molecular weight of the polymer. The cross-linked structure reduces excessive water solubility while maintaining sufficient viscosity-building capability, thereby improving weight efficiency and reducing the total polymer amount required in the formulation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This composition achieves higher viscosity with less polymer, reducing soil redeposition and maintaining stability, thus enhancing the performance and appearance of fabric softening compositions.

Implementation Method 1

the polymer is a crosslinked water swellable cationic polymer

Methodology Applied
Scientific EffectWater swelling: Hydrogel

Implementation Method 2

a cross-linking agent concentration of from 500 ppm to 5000 ppm relative to the polymer

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP2373774B1Improvements relating to fabric conditioners
Publication Date: 2013.03.20 UNILEVER PLC
  • EP2373774B1 patent drawing
  • EP2373774B1 patent drawing
  • EP2373774B1 patent drawing

AI summary

A fabric conditioner composition comprising a polymer and a fabric softening active, characterised in that the polymer is a crosslinked water swellable cationic copolymer of at least one cationic monomer and optionally other monomers selected from non-ionic and anionic monomers, characterized in that the polymer comprises less than 25 % of water soluble polymers, by total weight of the polymer, and a cross-linking agent concentration of from 500 ppm to 5000 ppm relative to the polymer.