Crosslinked Energetic Binder Mechanical Strength

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Solution Overview

Problem

Developing solid propellants that maintain high energy performance and mechanical properties across a wide range of temperatures, particularly at cold and room temperatures, while avoiding detrimental trade-offs between properties such as energy performance and combustion characteristics.

Innovation Solution

Increasing the quantity of crosslinking catalyst in composite pyrotechnic products containing a crosslinked energetic polymer and energetic plasticizer, with organic energetic charges representing 50 to 70% of the composition, to enhance mechanical properties without impacting energy performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the plasticizer content of the binder is reduced to improve mechanical properties, then mechanical strength is improved, but energy performance decreases

Engineering Contradiction:
Improvemechanical strengthVSAvoidenergy performance
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the binder system by introducing a polyisocyanate crosslinking agent and a crosslinking catalyst. This creates a crosslinked polymer network that fundamentally alters the mechanical properties of the binder, allowing high strength without sacrificing energy performance. The crosslinking density and catalyst amount are optimized to achieve the desired balance between mechanical strength and energy characteristics.

Inventive Principle:
Principle #35Parameter changes

2Strength

If a crosslinking agent is added to improve mechanical properties, then mechanical strength is improved, but the complexity of the formulation increases

Engineering Contradiction:
Improvemechanical strengthVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent introduces a crosslinking catalyst as an intermediary substance that facilitates the crosslinking reaction between the polyisocyanate crosslinking agent and the binder polymer. The catalyst (typically metal-based compounds at 0.1-5 wt%) mediates the chemical reaction, enabling crosslinking to proceed under milder conditions with better control over the reaction kinetics. This intermediary approach allows for more manageable formulation complexity while achieving the desired mechanical enhancement.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If the crosslinking catalyst amount is increased to improve mechanical properties at cold temperatures, then mechanical strength at cold temperature is improved, but the risk of unwanted side reactions increases

Engineering Contradiction:
Improvemechanical strength at cold temperatureVSAvoidside reaction control
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the amount of crosslinking catalyst within a specific range (0.1-5 wt% relative to the crosslinking agent) to achieve adequate mechanical strength at cold temperatures while suppressing unwanted side reactions. This parameter optimization balances the competing requirements of cold-temperature performance and formulation stability, preventing excessive crosslinking or decomposition that would compromise reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in composite pyrotechnic products with excellent mechanical properties at various temperatures, maintaining energy performance and enabling industrial-scale manufacturing, suitable for use as solid propellants in tactical missiles.

Implementation Method 1

The cross-linked energy polymer consists of a glycidyl polyazide (PAG), having a number-average molecular weight (Mn) between 700 and 3000 g/mol, obtained by cross-linking, away its terminal hydroxyl functions, using at least one polyisocyanate-type crosslinking agent

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

said energy polymer being crosslinked in the presence of 150 to 400 ppm of at least one crosslinking catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP3753916B1Composite pyrotechnical product
Publication Date: 2022.03.09 ARIANEGRP SAS
  • EP3753916B1 patent drawingFigure 1

AI summary

The invention relates to a composite pyrotechnic product containing organic energy charges in a plasticized binder, comprising a crosslinked energy polymer and at least one energy plasticizer, said crosslinked energy polymer consisting of a glycidyl polyazuride (PAG), having a number-average molecular weight (Mn) between 700 and 3000 g/mol, obtained by crosslinking, via its terminal hydroxyl functions, with at least one polyisocyanate-type crosslinking agent, in the presence of 150 ppm to 500 ppm of at least one crosslinking catalyst.