Crosslinked Organic Molecules for Image Sensor Light Absorption

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Solution Overview

Problem

Silicon photodiodes in image sensors have limited sensitivity due to small absorption areas, necessitating the development of alternative organic materials that can enhance light absorption and wavelength selectivity.

Innovation Solution

An optoelectronic material comprising crosslinked first and second organic molecules, specifically thiophene derivatives, which selectively absorb light in visible ray regions, including blue, red, and green wavelengths, thereby improving light absorption characteristics and wavelength selectivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If silicon photodiode is used in image sensor, then device structure is simple and manufacturing isๆˆ็†Ÿ, but absorption area is small and sensitivity is deteriorated

Engineering Contradiction:
ImprovesensitivityVSAvoidabsorption area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent changes the material parameters by using organic compounds with specific molecular structures (thiophene derivatives with electron donor and acceptor units) that have high extinction coefficients and strong light absorption capabilities, allowing for improved sensitivity without requiring larger pixel areas

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organic materials consisting of electron donor units and electron acceptor units connected through conjugated bonds, creating a material system with enhanced light absorption properties that overcomes the limitations of conventional silicon photodiodes

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If organic material is used to replace silicon photodiode, then light absorption characteristics are improved, but wavelength selectivity must be enhanced

Engineering Contradiction:
Improvelight absorptionVSAvoidwavelength selectivity
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The patent applies local quality by designing specific molecular structures with electron donor and electron acceptor units at different positions, where each unit contributes specific optical properties, enabling the material to selectively absorb certain wavelengths while maintaining strong overall absorption

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent modifies the optical parameters by adjusting the molecular structure of the organic compound, specifically by selecting appropriate electron donor and acceptor units and their connectivity, which controls the wavelength selectivity and absorption characteristics of the material

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The crosslinked organic molecules enhance light absorption and prevent crystallization, resulting in high external quantum efficiency and selective absorption in narrow wavelength regions, improving photoelectric conversion efficiency in image sensors.

Implementation Method 1

the first organic molecule and the second organic molecule having wavelength selectivity in a visible ray region

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

An optoelectronic device converts light into an electrical signal

Methodology Applied
Scientific EffectPhotoelectric conversion: Photoelectric Effect

Data Source

PatentUS10000462B2Optoelectronic material and organic optoelectronic device and image sensor
Publication Date: 2018.06.19 SAMSUNG ELECTRONICS CO LTD
  • US10000462B2 patent drawing
  • US10000462B2 patent drawing
  • US10000462B2 patent drawing

AI summary

An optoelectronic material includes a first organic molecule and a second organic molecule crosslinked with each other, the first organic molecule and the second organic molecule having wavelength selectivity in a visible ray region.