Crosslinked PE Foam Composition for High-Filler Shockpads

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Solution Overview

Problem

Conventional shock-absorbing materials in footwear and artificial turf lack improved mechanical properties and methods for high filler loadings, leading to suboptimal performance in terms of shock absorption and durability.

Innovation Solution

Crosslinked foams are developed using polyolefins with specific crystallinity and viscosity, combined with fillers, and optionally scorch retarders, to create dimensionally stable and cost-effective materials for footwear and turf applications, enhancing mechanical properties and processing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional shock-absorbing materials are used in footwear and artificial turf, then basic shock absorption function is provided, but mechanical properties and durability are insufficient

Engineering Contradiction:
Improvemechanical propertiesVSAvoiddurability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent employs composite materials by combining polyolefin base polymers with high concentrations of filler materials (such as calcium carbonate, silica, or metal oxides) to create a composite foam system. This composite structure provides both the shock absorption functionality of the polymer matrix and the enhanced mechanical properties and durability from the filler particles, directly resolving the contradiction between basic function and improved performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by systematically varying the filler loading concentration (from 20-80 wt%), filler particle size distribution, and crosslinking degree to optimize the balance between mechanical strength and durability. By adjusting these parameters, the material achieves superior mechanical properties while maintaining reliable long-term performance in footwear and turf applications.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If high filler loadings are used to improve mechanical properties, then cost-effectiveness and dimensional stability improve, but processing difficulty increases

Engineering Contradiction:
Improvecost-effectivenessVSAvoidprocessing difficulty
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by optimizing the filler particle size distribution and utilizing filler pre-aggregation techniques to reduce processing viscosity. By controlling these parameters, the patent enables high filler loadings (20-80 wt%) to be incorporated while maintaining ease of manufacturing and dimensional stability, effectively resolving the contradiction between cost-effectiveness and processing difficulty.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high filler loadings are used to enhance durability, then shock absorption performance improves, but processing time increases

Engineering Contradiction:
ImprovedurabilityVSAvoidcycle times
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent utilizes parameter changes by optimizing the filler particle size distribution and employing efficient mixing and processing techniques that reduce cycle times despite high filler loadings. By carefully controlling these parameters, the patent achieves enhanced durability and shock absorption performance while maintaining productive manufacturing cycle times.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The crosslinked foams exhibit improved shock absorption, durability, and reduced cycle times during processing, meeting FIFA standards for artificial turf and providing suitable properties for footwear, while maintaining low water uptake and dimensional stability.

Implementation Method 1

The crosslinked foams exhibit improved shock absorption

Methodology Applied
Scientific EffectShock absorption: Damping

Implementation Method 2

Crosslinked foams are developed using polyolefins with specific crystallinity and viscosity, combined with fillers

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 3

maintaining low water uptake and dimensional stability

Methodology Applied
Scientific EffectWater uptake: Absorption (physical)

Data Source

PatentEP2231755B1Pe-based crosslinked elastomeric foam with high filler loadings for making shockpads and articles used in footwear and flooring applications
Publication Date: 2011.06.15 DOW GLOBAL TECHNOLOGIES LLC
  • EP2231755B1 patent drawingFigure 1~2
  • EP2231755B1 patent drawingFigure 3~4
  • EP2231755B1 patent drawingFigure 5~6

AI summary

Crosslinked foams having high filler loadings, which may be formed from A) a polyolefin having a crystallinity of 21 percent or less, an ethylene vinyl acetate copolymer having a vinyl acetate content of less than 15 mole percent, or a combination thereof; B) a polyolefin having a viscosity between 500 and 20,000 cP, as measured using ASTM D 1084 (Brookfield Viscosity at 3500F); and C) a filler, wherein the crosslinked foam includes from 10 to 80 parts filler per hundred parts of components A, B, and C, by weight. In other aspects of embodiments disclosed herein, the crosslinked foam may optionally include one or more of: D) at least one polyolefin having a crystallinity of greater than 21 weight percent, an ethylene vinyl acetate copolymer having a vinyl acetate content of 15 mole percent or greater, or a combination thereof; and E) a scorch retarder.