Highly Crosslinked Polyethylene Particulate for Fracturing

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Solution Overview

Problem

Conventional polyethylene exhibits softness, flow, and agglomeration under high stress and temperature, making it unsuitable for certain applications where hardness and reduced flow are desired.

Innovation Solution

Development of highly crosslinked polymer particulate with polyethylene polymer chains that include chemical crosslinks, which covalently bond polyethylene chains, enhancing mechanical and thermal properties and preventing agglomeration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional polyethylene is used, then it exhibits softness and flexibility, but it flows and agglomerates under high stress and temperature

Engineering Contradiction:
ImprovehardnessVSAvoidresistance to flow and agglomeration
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent applies chemical crosslinking to transform the molecular structure of polyethylene, changing the physical and chemical parameters of the material. This crosslinking creates a three-dimensional network structure that fundamentally alters the material's response to stress and temperature, preventing chain slippage and molecular reorganization that cause flow and agglomeration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure at the molecular level by forming covalent bonds between polyethylene chains. This composite network structure combines the desirable properties of polyethylene with the structural stability of crosslinked networks, achieving both hardness and resistance to flow/agglomeration simultaneously.

Inventive Principle:
Principle #40Composite materials

2Strength

If polyethylene is chemically crosslinked to improve mechanical and thermal properties, then hardness and strength increase, but the material may become too rigid for certain applications

Engineering Contradiction:
Improvemechanical strengthVSAvoidapplication range
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent employs controlled crosslinking that creates local variations in crosslink density within the polyethylene structure. This allows different regions of the material to have different properties - some areas provide strength and hardness while other areas maintain flexibility and adaptability, enabling the material to meet diverse application requirements.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies partial crosslinking rather than complete crosslinking of all polyethylene chains. This partial action approach maintains sufficient flexibility and adaptability while achieving the necessary mechanical strength improvement, avoiding the excessive rigidity that would result from complete crosslinking.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The highly crosslinked polyethylene particulate demonstrates improved hardness, reduced flow, and decreased agglomeration, maintaining stability under stress and temperature, suitable for applications such as hydraulic fracturing and wellbore operations.

Implementation Method 1

The plurality of chemical crosslinks includes chemical crosslinks that covalently bond a given polyethylene polymer chain of the plurality of polyethylene polymer chains to another polyethylene polymer chain of the plurality of polyethylene polymer chains

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Data Source

PatentUS20210047480A1Highly Crosslinked Polymer Particulate
Publication Date: 2021.02.18 EXXONMOBIL TECHNOLOGY & ENGINEERING CO

AI summary

Highly crosslinked polymer particulate. The highly crosslinked polymer particulate includes a plurality of crosslinked polymer granules. The crosslinked polymer granules include a highly crosslinked polymeric material. A characteristic dimension of each crosslinked polymer granule of the plurality of crosslinked polymer granules is at least 10 micrometers and at most 5 millimeters.