Crosslinked Polyethylene Pipe Composition for High Pressure Resistance

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Solution Overview

Problem

Existing crosslinked polyethylene pipes, particularly PE-Xa, face challenges in achieving high melt index and density while maintaining a sufficient degree of crosslinking, which affects pressure resistance and physical properties.

Innovation Solution

A crosslinked polyethylene pipe is developed with specific molecular weight and density ranges, using a hybrid metallocene catalyst system to enhance melt index and density, ensuring a high degree of crosslinking and improved pressure resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If polyethylene with high melt index is used to increase density and improve pressure resistance, then pressure resistance is improved, but the degree of crosslinking is lowered

Engineering Contradiction:
Improvepressure resistanceVSAvoiddegree of crosslinking
Core Design Contradiction:
Stress or pressureVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the melt index within the range of 1-20 g/10min and density within 0.940-0.960 g/cm³. This optimization balances the chain mobility needed for high density with sufficient molecular weight to maintain crosslinking degree, resolving the contradiction between pressure resistance and crosslinking quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite approach by combining polyethylene with specific molecular weight distribution and controlled low molecular weight content with optimized crosslinking agents. This creates a composite material system where the polyethylene base provides density and pressure resistance while the controlled composition ensures adequate crosslinking degree

Inventive Principle:
Principle #40Composite materials

2Stress or pressure

If polyethylene with high density is used to improve pressure resistance, then pressure resistance is improved, but chain mobility is reduced

Engineering Contradiction:
Improvepressure resistanceVSAvoidchain mobility
Core Design Contradiction:
Stress or pressureVSSpeed

Solution Approach 1:

The patent optimizes the melt index parameter within 1-20 g/10min to balance density and chain mobility. This controlled parameter range ensures sufficient chain mobility for processing and flexibility while achieving the required density for pressure resistance, resolving the contradiction between these two properties

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If a large amount of low molecular weight is produced to increase chain mobility and density, then density is improved, but the degree of crosslinking is lowered

Engineering Contradiction:
ImprovedensityVSAvoiddegree of crosslinking
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent controls the low molecular weight content within 20-40% of the total molecular weight distribution. This parameter optimization ensures sufficient chain mobility and density while maintaining enough high molecular weight content to achieve adequate crosslinking degree, resolving the contradiction between quantity and quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by creating a bimodal molecular weight distribution where different portions of the polymer chains serve different functions: lower molecular weight portions provide chain mobility and density, while higher molecular weight portions ensure crosslinking degree. This local differentiation of molecular weight qualities resolves the contradiction

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polyethylene exhibits excellent strength and pressure resistance, suitable for producing flexible PE-Xa pipes with enhanced crosslinking properties.

Implementation Method 1

a first metallocene compound and a second metallocene compound

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

crosslinked polyethylene which is modified into polyethylene having a three-dimensional network structure by crosslinking

Methodology Applied
Scientific EffectCrosslinking reaction: Chemical Bonding

Data Source

PatentEP3882281B1Polyethylene having high pressure resistance and crosslinked polyethylene pipe comprising the same
Publication Date: 2025.11.26 LG CHEM LTD
  • EP3882281B1 patent drawing
  • EP3882281B1 patent drawing
  • EP3882281B1 patent drawing

AI summary

The present disclosure relates to a polyethylene having high pressure resistance and a crosslinked polyethylene pipe including the same. The polyethylene according to the present disclosure has high melt index and density and exhibits a sufficient degree of crosslinking, thereby exhibiting excellent strength and pressure resistance characteristics.