Crosslinked PTFE Sliding Member via Ionizing Radiation

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Solution Overview

Problem

Current polytetrafluoroethylene (PTFE) materials lack sufficient wear resistance and mechanical strength for advanced sliding applications, necessitating the development of a PTFE formed product with enhanced properties for use in sliding members.

Innovation Solution

A PTFE formed product is created by irradiating a forming material with ionizing radiation, utilizing low-molecular weight PTFE as the principal component, which results in a crosslinked structure with improved molecular entanglement, achieving higher wear resistance and mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high-molecular weight PTFE is used to provide sufficient mechanical strength through molecular entanglement, then strength is improved, but wear resistance remains insufficient for advanced sliding applications

Engineering Contradiction:
Improvemechanical strengthVSAvoidwear resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter of PTFE from high (conventional) to low (600 thousand or less), and combines it with ionizing radiation treatment to create a crosslinked structure. This parameter change enables low-molecular weight PTFE to achieve both sufficient mechanical strength and superior wear resistance, resolving the contradiction between strength and wear resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional reliance on molecular entanglement (mechanical strength mechanism) with a crosslinked structure formed by ionizing radiation. This substitution allows the material to achieve mechanical strength through chemical crosslinking rather than just physical entanglement, enabling better wear resistance while maintaining strength.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Ease of operation

If low-molecular weight PTFE is used as an additive for improving slidability and coating film texture, then slidability is improved, but mechanical strength becomes insufficient

Engineering Contradiction:
ImproveslidabilityVSAvoidmechanical strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent replaces the insufficient mechanical strength of low-molecular weight PTFE with a crosslinked structure formed by ionizing radiation treatment. This substitution transforms the material's strength mechanism from relying on molecular entanglement to relying on crosslinking bonds, enabling low-molecular weight PTFE to achieve both good slidability and sufficient mechanical strength.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the molecular weight parameter to low (600 thousand or less) for improved slidability, and compensates for the strength deficiency through ionizing radiation treatment. This combined approach allows the material to achieve both improved slidability and sufficient mechanical strength simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional PTFE materials are used for sliding members, then manufacturing is simple, but wear resistance and mechanical strength are insufficient for high-durability applications

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidwear resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies ionizing radiation treatment to the PTFE forming material before or during the forming process to create a crosslinked structure in advance. This preliminary action ensures that the material possesses the required wear resistance and mechanical strength before being formed into the final sliding member product, achieving high durability without complicating the manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting PTFE formed product exhibits a PV limit of not less than 1600 MPa·m/min, pencil hardness of at least HB, and elongation at break of 100%, making it suitable for high-durability sliding members with improved wear resistance and productivity.

Implementation Method 1

a crosslinked PTFE formed by crosslinking of the PTFE chains in the PTFE forming material upon irradiation with ionizing radiation

Methodology Applied
Scientific EffectIonizing radiation: Radiation

Implementation Method 2

crosslinking of the PTFE chains in the PTFE forming material upon irradiation with ionizing radiation

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP3348601B1Polytetrafluoroethylene molded body, and manufacturing method therefor
Publication Date: 2021.05.19 SUMITOMO ELECTRIC FINE POLYMER INC
  • EP3348601B1 patent drawing
  • EP3348601B1 patent drawing

AI summary

A polytetrafluoroethylene formed product according to an aspect of the invention contains, as a principal component, a polytetrafluoroethylene having a crosslinked structure and has a PV limit of not less than 1600 MPa·m/min.