Crosslinking Agent Masterbatch with Ultrasound Markers

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Solution Overview

Problem

Existing crosslinking agent masterbatches in rubber mixtures cannot be effectively monitored for dispersion quality in real-time during the production process, limiting the ability to ensure consistent quality and efficiency in rubber mixture production.

Innovation Solution

Incorporating pulverulent marker substances with high densities, such as tungsten carbides and barium sulfate, into crosslinking agent masterbatches allows for online detection of dispersion quality using ultrasound and other methods, ensuring homogeneous mixing and quality control.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If separate production of crosslinking agent masterbatches is used to continuously introduce into parent mixtures, then practical production and performance are improved, but online detection of dispersion quality cannot be achieved

Engineering Contradiction:
Improvecontinuous production capabilityVSAvoiddispersion quality detection
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent introduces marker substances as intermediary particles with distinct acoustic properties that mediate between the crosslinking agent masterbatch and the ultrasound detection system. These marker particles scatter ultrasound waves in a detectable manner, enabling indirect measurement of dispersion quality without interfering with the crosslinking process or production continuity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces offline mechanical/visual inspection methods with online ultrasound acoustic detection. By substituting physical sampling and laboratory analysis with continuous acoustic field measurement, the system achieves real-time dispersion quality monitoring while maintaining continuous production operations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Device complexity

If traditional crosslinking agent masterbatches are used without marker substances, then production process is simpler, but quality control requires offline testing only

Engineering Contradiction:
Improvemasterbatch composition simplicityVSAvoidquality feedback time
Core Design Contradiction:
Device complexityVSLoss of time

Solution Approach 1:

The patent incorporates marker substances into the crosslinking agent masterbatch formulation in advance, before the dispersion quality needs to be measured. This preliminary inclusion of detection markers enables immediate online monitoring upon introduction into the rubber compound, eliminating the time delay associated with offline sampling and laboratory analysis.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Marker substances serve as intermediary agents that bridge the gap between the crosslinking agent distribution and the ultrasound detection system. These particles provide acoustic contrast that allows indirect measurement of crosslinking agent dispersion quality without requiring direct measurement of the crosslinking agents themselves.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If marker substances are added to enable online detection, then dispersion quality monitoring is improved, but masterbatch composition becomes more complex

Engineering Contradiction:
Improvedispersion quality detection accuracyVSAvoidmasterbatch formulation complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies local quality by concentrating marker substances specifically within the crosslinking agent masterbatch phase rather than distributing them throughout the entire rubber compound. This localized placement ensures that markers are co-introduced with crosslinking agents, providing accurate local dispersion measurements while minimizing overall formulation complexity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by selecting marker substances with specific acoustic properties (density, compressibility) that differ from both the crosslinking agents and the rubber matrix. This acoustic parameter differentiation enables selective detection of marker particles via ultrasound, providing measurement capability without requiring complex formulation adjustments.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables real-time monitoring and control of crosslinking agent dispersion within rubber mixtures, enhancing production efficiency and consistency by facilitating continuous and inline quality assessment, reducing the risk of production failures.

Implementation Method 1

allows for online detection of dispersion quality using ultrasound

Methodology Applied
Scientific EffectUltrasound scattering: Ultrasound

Data Source

PatentUS9388290B2Batches of cross-linking agents, containing marking substances, novel cross-linkable rubber mixtures, method for the production thereof, and use of same
Publication Date: 2016.07.12 LANXESS DEUTSCHLAND GMBH
  • US9388290B2 patent drawing
  • US9388290B2 patent drawing
  • US9388290B2 patent drawing

AI summary

The invention relates to novel batches of cross-linking agents, containing marking substances, to novel cross-linkable rubber mixtures, to a method for the production thereof and to the use of same.