Crude Oil Demulsifier Characterization Using Cylindrical Sensor

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Solution Overview

Problem

The co-extraction of water with hydrocarbons from oil and gas wells requires expensive separation, treatment, and disposal processes, and existing methods for evaluating demulsifiers are inefficient, leading to increased costs and reduced quality of dry crude oil products.

Innovation Solution

A system and method using a cylindrical sensor with a fluoropolymer coating to measure density changes over time in a sample of crude oil and demulsifier, allowing for the determination of emulsion breaking efficiency, which includes a computer-controlled tensiometer and heater to maintain specified temperature and stirring conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional demulsifier evaluation methods are used, then testing procedures are simple, but measurement precision and reliability are insufficient

Engineering Contradiction:
Improveemulsion breaking efficiency measurementVSAvoidtesting system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces manual visual evaluation methods with an automated optical detection system. A light source illuminates the sample, and a photodetector measures light transmission through the sample. As the demulsifier breaks the emulsion and separates water from oil, the optical properties change, providing precise quantitative measurement of emulsion breaking efficiency without requiring complex manual assessment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces an optical intermediary system (light source and photodetector) to measure demulsifier performance. Instead of directly observing separation, the system uses light transmission as an intermediary parameter that correlates with emulsion stability and breaking efficiency, enabling indirect but precise measurement of the separation process.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If more demulsifier is used to improve separation, then emulsion breaking efficiency increases, but operational costs increase

Engineering Contradiction:
Improveseparation qualityVSAvoidoperational cost
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent implements a feedback mechanism where the optical detection system continuously monitors emulsion breaking progress in real-time. The measured light transmission data is fed back to determine when optimal separation has been achieved, allowing operators to stop the process at the precise moment of effectiveness. This prevents unnecessary continued operation and excessive demulsifier usage, optimizing both separation quality and operational cost.

Inventive Principle:
Principle #23Feedback

3Reliability

If extensive separation and treatment processes are used, then water removal is thorough, but operational costs and time increase

Engineering Contradiction:
Improvewater removal effectivenessVSAvoidprocessing speed
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent performs preliminary demulsification action by allowing the demulsifier to work on the emulsion under controlled conditions before further processing. The optical monitoring system detects the completion of this preliminary separation stage, enabling early termination of the demulsifier action. This preliminary action achieves significant water removal efficiency without requiring prolonged processing times or multiple treatment stages.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables efficient testing of demulsifiers, improving dry crude oil product quality, reducing demulsifier usage, and lowering operational costs by accurately assessing emulsion breaking efficiency, thereby optimizing gas oil separation processes.

Implementation Method 1

A cylindrical sensor with a fluoropolymer coating measures changes in density of the sample over time

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Implementation Method 2

An external surface of the cylindrical sensor includes a fluoropolymer

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS11852648B2Crude oil demulsifier characterization
Publication Date: 2023.12.26 SAUDI ARABIAN OIL CO
  • US11852648B2 patent drawing
  • US11852648B2 patent drawing
  • US11852648B2 patent drawing

AI summary

A sample is placed in a sample housing. The sample includes crude oil and a demulsifier. A cylindrical sensor is submerged in the sample within the sample housing. An external surface of the cylindrical sensor includes a fluoropolymer. A plurality of densities of the sample are measured by a computer for a corresponding plurality of time points over a specified testing time duration. The computer is communicatively coupled to the cylindrical sensor. The plurality of densities and the corresponding plurality of times points are recorded by the computer. An emulsion breaking efficiency of the demulsifier is determined based on the recorded plurality of densities and corresponding plurality of time points.