Crystal Oscillator Sensor for Chemical Liquid Purity Management

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for evaluating the purity of high-purity chemical liquids used in semiconductor manufacturing, such as those described in Patent Document 1, are complex, time-consuming, and lack general-purpose applicability, making them impractical for frequent use in industrial settings.

Innovation Solution

A management method involving a crystal oscillator sensor with an adsorption layer that measures impurity levels by detecting changes in resonance frequency, where the sensor is brought into contact with the chemical liquid, and the results are compared against a preset range to determine purity, with components made of materials like Si, Au, or fluorine-based resins to enhance accuracy and ease of use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a surface inspection device is used to evaluate chemical liquid purity, then measurement accuracy is improved, but measurement time increases and device complexity increases

Engineering Contradiction:
Improvepurity evaluation accuracyVSAvoidmeasurement time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent replaces the complex mechanical surface inspection device with a crystal oscillator-based sensing system. The crystal oscillator sensor detects impurities through resonance frequency changes, substituting mechanical/optical inspection with a simpler vibrational measurement approach that achieves comparable purity evaluation accuracy with reduced measurement time and device complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the measurement parameter from visual/optical defect detection to resonance frequency detection. By monitoring frequency shifts of the crystal oscillator when exposed to chemical liquids, the system achieves accurate purity evaluation through a different physical parameter that requires simpler equipment and faster measurement cycles.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If a surface inspection device is used to evaluate chemical liquid purity, then measurement accuracy is improved, but device complexity increases

Engineering Contradiction:
Improvepurity evaluation accuracyVSAvoidmeasurement system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces the complex mechanical surface inspection device with a crystal oscillator-based sensing system. The crystal oscillator sensor detects impurities through resonance frequency changes, substituting mechanical/optical inspection with a simpler vibrational measurement approach that achieves comparable purity evaluation accuracy with reduced measurement time and device complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention extracts the essential measurement function from the complex surface inspection device, isolating only the critical sensing capability. By using a crystal oscillator that directly responds to impurity presence through frequency changes, the system removes unnecessary mechanical and optical components while retaining the core purity evaluation function.

Inventive Principle:
Principle #2Taking out (Extraction)

3Measurement precision

If conventional purity evaluation methods are used, then measurement accuracy is maintained, but ease of operation deteriorates

Engineering Contradiction:
Improvepurity measurement accuracyVSAvoidoperational simplicity
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The crystal oscillator sensor performs self-diagnosis through its resonance frequency response. When exposed to chemical liquids, the oscillator automatically detects impurities and generates a measurable frequency shift, eliminating the need for complex operational procedures. The system serves itself by directly transducing impurity presence into a readable signal without requiring elaborate measurement protocols.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention changes the measurement parameter from visual/optical defect detection to resonance frequency detection. By monitoring frequency shifts of the crystal oscillator when exposed to chemical liquids, the system achieves accurate purity evaluation through a different physical parameter that requires simpler equipment and faster measurement cycles.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the evaluation of chemical liquid purity, reducing measurement time and improving industrial applicability by providing a more efficient and reliable method for managing the purity of chemical liquids containing organic solvents.

Implementation Method 1

obtaining an amount of change in a resonance frequency of the crystal oscillator resulting from contact of the target chemical liquid

Methodology Applied
Scientific EffectResonance frequency change: Resonance

Implementation Method 2

a crystal oscillator sensor including an adsorption layer that adsorbs the impurities

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12188901B2Management method, measuring method, measuring device, crystal oscillator sensor, and set
Publication Date: 2025.01.07 FUJIFILM CORP
  • US12188901B2 patent drawing
  • US12188901B2 patent drawing
  • US12188901B2 patent drawing

AI summary

A management method of managing a purity of a chemical liquid containing an organic solvent by sensing impurities in the chemical liquid. The management method includes Step 1 of preparing a target chemical liquid containing an organic solvent; Step 2 of bringing the target chemical liquid into contact with a crystal oscillator sensor including an adsorption layer that adsorbs the impurities and a crystal oscillator and obtaining an amount of change in a resonance frequency of the crystal oscillator resulting from contact of the target chemical liquid; and Step 3 of managing the purity of the chemical liquid by comparing whether or not the obtained amount of change falls within a permissible range based on a preset purity of the target chemical liquid. In Step 2, at least a part of a liquid contact portion coming into contact with the target chemical liquid is made of a fluorine-based resin.