Crystalline Interfacial Passivation for III-V HEMT Reliability

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Solution Overview

Problem

Current methods for passivating III-V semiconductor compounds in HEMTs result in high interfacial density of states, leading to device performance issues such as drain current degradation and threshold voltage fluctuations.

Innovation Solution

The method involves epitaxially growing buffer and III-V compound layers, in-situ treating native oxide layers to form crystalline oxide layers, and forming crystalline interfacial and dielectric passivation layers to reduce interfacial density of states, thereby improving the reliability and performance of HEMTs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional passivation methods are used on III-V compounds, then the surface is protected from ambient air reaction, but the interfacial density of states becomes undesirably high causing device performance degradation

Engineering Contradiction:
Improvesurface protectionVSAvoidinterfacial density of states
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

A crystalline interfacial layer is formed on the III-V compound surface before the passivation layer is applied. This preliminary crystalline structure reduces the interfacial density of states and prevents the formation of high-density amorphous interfaces that would otherwise occur with conventional direct passivation methods

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the structural parameter of the interface from amorphous to crystalline by forming a crystalline interfacial layer. This parameter change significantly reduces the interfacial density of states while maintaining effective surface protection against ambient air reaction

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional passivation is applied directly to III-V compounds, then manufacturing is simplified, but threshold voltage fluctuation and off-current leakage increase

Engineering Contradiction:
Improvepassivation process simplicityVSAvoidthreshold voltage stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The crystalline interfacial layer is formed as a preliminary step before passivation, creating a stable interface that reduces threshold voltage fluctuation and off-current leakage while maintaining manufacturing feasibility through integrated process steps

Inventive Principle:
Principle #10Preliminary action

3Reliability

If amorphous native oxide layers are left on III-V compounds, then the surface is naturally passivated, but device performance degrades due to high interfacial density of states

Engineering Contradiction:
Improvenatural passivationVSAvoidinterface quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent transforms the amorphous native oxide layer into a crystalline interfacial layer through controlled formation processes. This parameter change from amorphous to crystalline structure maintains natural passivation while dramatically improving interface quality and reducing interfacial density of states

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The native oxide layer, which would normally be considered a harmful defect causing high interfacial density of states, is converted into a beneficial crystalline interfacial layer that provides both protection and low interface states when properly formed and integrated into the device structure

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces interfacial density of states, stabilizes threshold voltage, and enhances the reliability and performance of HEMTs by converting amorphous native oxide layers into crystalline structures within the HEMT manufacturing process.

Implementation Method 1

in-situ treating native oxide layers to form crystalline oxide layers

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Implementation Method 2

epitaxially growing buffer and III-V compound layers

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS11575021B2Surface treatment and passivation for high electron mobility transistors
Publication Date: 2023.02.07 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11575021B2 patent drawing
  • US11575021B2 patent drawing
  • US11575021B2 patent drawing

AI summary

A semiconductor device includes a compound semiconductor layer comprising a III-V material; a first layer on the compound semiconductor layer and comprising oxygen, nitrogen, and a material included in the compound semiconductor layer; a second layer over the first layer, wherein at least a portion of the second layer comprises a single crystalline structure or a polycrystalline structure; a dielectric layer over the second layer; and a source/drain electrode extending through the dielectric layer, the second layer, and the first layer and into the compound semiconductor layer.