Crystalline Passivation Layer for III-N Surface Trap Reduction

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Solution Overview

Problem

III-N high-electron-mobility transistors face performance degradation due to strain-induced interface trap states caused by lattice mismatch between heterojunction materials, leading to electron trapping and channel depletion.

Innovation Solution

A crystalline passivation layer with a lattice constant matching the III-nitride material is formed to terminate dangling bonds and reduce surface traps, improving the interface quality between the III-N surface and the gate dielectric, which can be deposited using techniques like atomic layer deposition or chemical vapor deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a heterojunction is formed between III-N materials with different band gaps, then high electron mobility is achieved, but lattice mismatch causes strain-induced interface trap states that degrade device performance

Engineering Contradiction:
Improveelectron mobilityVSAvoiddevice performance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

A crystalline passivation layer is introduced as an intermediary between the III-N heterojunction and the external environment. This layer has a lattice constant that matches the III-nitride material, providing a buffer that reduces strain at the interface and prevents harmful interactions while maintaining the high electron mobility channel.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical and chemical parameters of the surface by forming a crystalline passivation layer with specific lattice constant matching the III-nitride material. This parameter change reduces the strain-induced interface trap states while preserving the beneficial electronic properties of the heterojunction.

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If the III-N surface is left exposed, then device structure is simplified, but surface traps cause electron trapping and channel depletion

Engineering Contradiction:
Improvedevice structureVSAvoiddevice performance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The crystalline passivation layer serves as a protective intermediary between the III-N surface and the external environment. It terminates dangling bonds and reduces surface traps without significantly increasing device complexity, as it can be integrated into existing fabrication processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The passivation layer is formed as a preliminary step before final device assembly and operation. By pre-passivating the surface, the patent prevents electron trapping and channel depletion from occurring during device operation, ensuring reliable performance from the outset.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If a passivation layer is deposited to reduce surface traps, then interface quality improves, but additional manufacturing steps are required

Engineering Contradiction:
Improveinterface qualityVSAvoidfabrication process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent achieves high interface quality by controlling the lattice constant parameter of the passivation layer to match the III-nitride material. This parameter control can be accomplished through standard epitaxial growth techniques, balancing manufacturing precision with ease of manufacture.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The crystalline passivation layer provides a homogeneous interface with the III-N surface, ensuring uniform passivation across the device area. This homogeneity improves interface quality while using conventional deposition methods that are already integrated into III-N device fabrication workflows.

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The crystalline passivation layer effectively reduces interfacial traps, enhances device performance by minimizing electron trapping, and improves the coherence of surface bonds, leading to better conductivity and reliability in III-N HEMT devices.

Implementation Method 1

A crystalline passivation layer is formed on a III-N surface that reduces the effects of surface traps as well as create a good interface between a III-N surface and an insulator. The crystalline passivation layer can have a lattice constant that matches with the III-nitride material and the dielectric layer on top of it, and hence provides suitable bond-matching to either side of the interface.

Methodology Applied
Scientific EffectLattice matching:

Implementation Method 2

which can be deposited using techniques like atomic layer deposition or chemical vapor deposition

Methodology Applied
Scientific EffectAtomic layer deposition:

Implementation Method 3

which can be deposited using techniques like atomic layer deposition or chemical vapor deposition

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS9130026B2Crystalline layer for passivation of III-N surface
Publication Date: 2015.09.08 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US9130026B2 patent drawing
  • US9130026B2 patent drawing
  • US9130026B2 patent drawing

AI summary

Some embodiments of the present disclosure relates to a crystalline passivation layer for effectively passivating III-N surfaces. Surface passivation of HEMTs reduces or eliminates the surface effects that can otherwise degrade device performance. The crystalline passivation layer reduces the degrading effects of surface traps and provides a good interface between a III-nitride surface and an insulator (e.g., gate dielectric formed over the passivation layer).