Crystallizable Polymer Phase Difference Film for Curved OLED Displays

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Solution Overview

Problem

The challenge is to create a multilayer film for organic electroluminescent display devices that prevents surface deformation, curling, and ensures favorable adhesion between the barrier layer and phase difference film while maintaining optical properties, especially for curved display surfaces.

Innovation Solution

A multilayer film comprising a phase difference film with a crystallizable polymer A, having a melting point of 250°C or higher, and specific optical properties, where the barrier layer is directly disposed on the phase difference film, and includes a ¼ wave plate and a ½ wave plate with oblique slow axes, and an inorganic barrier layer for enhanced adhesion and optical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of stationary object

If a resin substrate film is used instead of glass substrate to reduce weight and thickness, then the display device becomes lighter and thinner, but the barrier layer may deform or curl during formation

Engineering Contradiction:
Improveweight of display deviceVSAvoidsurface flatness of barrier layer
Core Design Contradiction:
Weight of stationary objectVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by carefully controlling the heating temperature during barrier layer formation to remain below the glass transition temperature of the resin substrate. This temperature parameter control prevents the resin from softening and deforming, thereby maintaining surface flatness while still enabling barrier layer deposition on the lightweight resin substrate

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs beforehand cushioning by pre-heating the resin substrate to a controlled temperature before barrier layer formation, and by designing the barrier layer formation process to occur at temperatures that prevent excessive thermal expansion or deformation of the resin substrate, thus cushioning against potential deformation issues

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

2Strength

If the barrier layer is formed at high temperature to ensure adhesion, then adhesion improves, but the resin substrate may deform or curl

Engineering Contradiction:
Improveadhesion between barrier layer and substrateVSAvoidflatness of substrate surface
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The patent changes the temperature parameter of barrier layer formation to occur below the glass transition temperature of the resin substrate. This parameter modification allows adhesion to be achieved through chemical bonding mechanisms at lower temperatures, preventing thermal deformation while maintaining strong adhesion between the barrier layer and resin substrate

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces thermal-mechanical adhesion (which would require high temperature and pressure) with chemical adhesion mechanisms that operate at lower temperatures. The barrier layer forms strong chemical bonds with the resin substrate through surface chemistry interactions, substituting mechanical compression-based adhesion with chemical bonding

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If a planar display surface is used, then manufacturing is easier, but curved display surfaces require flexible components that maintain optical properties

Engineering Contradiction:
Improveease of manufacturing display surfaceVSAvoidflexibility for curved surfaces
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The patent employs flexible thin films by using a resin substrate that can be manufactured in flexible forms. The barrier layer and phase difference film are deposited as thin flexible layers on this substrate, creating a multilayer structure that can bend and conform to curved surfaces while maintaining its optical properties and structural integrity

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent applies universality by designing a multilayer film structure that serves multiple functions: it provides barrier protection, maintains optical properties for display, and enables both planar and curved display surface configurations. The same structure adapts to different form factors without requiring separate component designs

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution prevents surface deformation and curling, ensures favorable adhesion, and maintains excellent optical and barrier properties, making it suitable for thin, flexible organic electroluminescent display devices with curved surfaces.

Implementation Method 1

the polymer A has a melting point of 250° C. or higher

Methodology Applied
Scientific EffectMelting point: Melting

Implementation Method 2

the layer of the resin A has an in-plane retardation Re of 108 nm or more and 168 nm or less measured with light having a wavelength of 590 nm at 23° C., and an absolute value of a photoelastic coefficient of 2.0×10−11 Pa−1 or less

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 3

a barrier layer for interfering with the transmission of moisture, oxygen, and the like is further disposed thereon

Methodology Applied
Scientific EffectPermeation barrier: Permeation

Data Source

PatentUS10522793B2Multilayer film, manufacturing method, circular-polarizing plate, antireflective film, and organic electroluminescence display device
Publication Date: 2019.12.31 ZEON CORP
  • US10522793B2 patent drawing
  • US10522793B2 patent drawing
  • US10522793B2 patent drawing

AI summary

A multilayer film for an organic electroluminescent display device, the multilayer film including: a phase difference film; and a barrier layer directly disposed on a surface of the phase difference film, wherein the phase difference film includes one or more layers of a resin A as a layer in direct contact with the barrier layer, the resin A includes a crystallizable polymer A having a melting point of 250° C. or higher, and the layer of the resin A has a specific value of in-plane retardation Re measured with light having a wavelength of 590 nm at 23° C., and an absolute value of a photoelastic coefficient of 2.0×10−11 Pa−1 or less; a production method therefor; and use thereof.