Crystallization Control via Impedance and Temperature Sensors

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Solution Overview

Problem

Chemical process engineering faces inefficiencies in product purification through crystallization due to impurity accumulation and energy wastage, as existing methods struggle to maintain optimal temperature control and monitor crystallization processes effectively, leading to reduced product purity and increased resource waste.

Innovation Solution

A device equipped with temperature and impedance sensors connected to a control and evaluation unit, allowing for online monitoring and control of crystallization processes by measuring total product concentration, solid fraction, dissolved product fraction, and impurity fraction, ensuring efficient crystallization and maintaining optimal process conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If the solution is reused to dissolve the next portion of contaminated product, then resource efficiency is improved, but impurity concentration accumulates and reduces product purity

Engineering Contradiction:
Improvesolvent wasteVSAvoidproduct purity
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The patent implements an online monitoring system using temperature and impedance sensors that continuously measure crystallization parameters and feed this information back to the control unit. This feedback mechanism enables real-time detection of impurity accumulation in reused solvent, allowing the system to optimize the reuse cycle and maintain product purity while maximizing solvent utilization.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts process parameters (temperature, crystallization time, solvent composition) based on real-time measurements of impurity concentration. By changing these parameters adaptively, the system can extend the useful life of reused solvent while preventing impurity accumulation from compromising product quality.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the product is held at the target temperature for longer time, then crystallization completeness is improved, but energy consumption increases

Engineering Contradiction:
Improvecrystallization completenessVSAvoidcooling energy
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The control unit receives real-time data from temperature and impedance sensors monitoring the crystallization process. Based on this feedback, the system determines when crystallization is complete and automatically stops the cooling process, preventing unnecessary energy consumption while ensuring complete crystallization.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The online monitoring system enables the crystallization process to self-regulate. The system automatically detects the endpoint of crystallization through impedance changes and adjusts the holding time accordingly, eliminating the need for manual intervention or fixed-time protocols that would waste energy.

Inventive Principle:
Principle #25Self-service

3Productivity

If temperature ramps are applied rapidly during crystallization, then process time is reduced, but control precision deteriorates

Engineering Contradiction:
Improvecrystallization speedVSAvoidtemperature control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent implements dynamic temperature control that adapts the cooling rate based on real-time process conditions. The system uses impedance measurements to detect crystallization stage and automatically adjusts the temperature ramp rate, enabling both rapid overall cooling and precise control during critical crystallization phases.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system dynamically changes temperature parameters (cooling rate, holding temperature, ramp speed) based on real-time feedback from sensors. This allows the process to achieve both high productivity through rapid initial cooling and high precision during the crystallization phase by adjusting the temperature profile adaptively.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If online monitoring of crystallization process is implemented, then process efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveprocess efficiencyVSAvoidsensor and control system
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs multi-functional sensors that simultaneously measure multiple parameters (temperature and electrical impedance) with a single device. The control unit integrates data from both sensors to provide comprehensive process monitoring and control, reducing the overall system complexity compared to using separate specialized sensors for each parameter.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables precise monitoring and control of the crystallization process, preventing impurity accumulation and maintaining product purity, thereby enhancing the efficiency of the purification process and reducing energy wastage.

Implementation Method 1

an impedance sensor (9) are arranged at at least two locations of the device (1), wherein the temperature sensors (8) and the impedance sensors (9) are connected to the control and evaluation unit (7)

Methodology Applied
Scientific EffectElectrical impedance measurement: Electrical Resistance

Implementation Method 2

a temperature sensor (8) and an impedance sensor (9) are arranged at at least two locations of the device (1), wherein the temperature sensors (8) and the impedance sensors (9) are connected to the control and evaluation unit (7)

Methodology Applied
Scientific EffectTemperature sensing: Thermocouple

Implementation Method 3

a crystallization unit (3) in which the product crystallizes during operation and thus forms a solid fraction (β)

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 4

If the solution or suspension in a crystallization unit is brought to a supersaturated state, for example by cooling or solvent evaporation, crystal formation or crystal growth is stimulated

Methodology Applied
Scientific EffectSupersaturation: Supersaturation

Data Source

PatentEP4112149A1Device for cleaning a product and method for cleaning a product
Publication Date: 2023.01.04 KROHNE MESSTECHNICK GMBH & CO KG
  • EP4112149A1 patent drawingFigure 1~2
  • EP4112149A1 patent drawingFigure 3~4
  • EP4112149A1 patent drawingFigure 5~6

AI summary

Described and illustrated is a device (1) for purifying a product by means of crystallization, wherein the product is preferably produced by a chemical process and wherein the product has an impurity content δ, comprising a feed unit (2) with a solvent, wherein in operation the product is fed to the device (1) via the feed unit (2) so that the total product concentration α is present in the solvent in the feed unit (2), a crystallization unit (3) in which the product crystallizes in operation and thus forms a solid fraction β, wherein a further fraction of the product is present as a dissolved product fraction γ, a separation unit (4) in which the crystallized product is separated from the solvent or the suspension, and a temperature control unit (6) by which the temperature can be controlled at least in the feed unit (2) and/or the crystallization unit (3).and further comprising a control and evaluation unit (7), characterized in that at least one temperature sensor (8) and one impedance sensor (9) are arranged at at least two locations of the device (2), wherein the temperature sensors (8) and the impedance sensors (9) are connected to the control and evaluation unit (7) and that the control and evaluation unit (7) is configured such that, during operation, it determines the total product concentration α and/or the concentration of the solid fraction β and/or the concentration of the dissolved product fraction γ and/or the concentration of the impurity fraction δ, taking into account the measured values ​​of the temperature sensors and the impedance sensors.