CsI Scintillator Tl Concentration Gradient for X-Ray Afterimage Reduction

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Solution Overview

Problem

Conventional X-ray detectors with CsI scintillator layers face challenges in improving overall characteristics, particularly afterimage characteristics, despite efforts to enhance sensitivity and resolution.

Innovation Solution

A radiation detector with a CsI scintillator layer having a Tl activator concentration of 1.6 mass% ±0.4 mass%, where the concentration is higher in the central portion than the peripheral portion, and maintained within ±15% in-plane and film thickness directions, optimized through vacuum vapor deposition using multiple evaporation sources, to improve afterimage, sensitivity, and resolution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the activator concentration is increased to improve sensitivity, then the luminous efficiency improves, but the afterimage characteristics deteriorate

Engineering Contradiction:
ImprovesensitivityVSAvoidafterimage
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating a non-uniform activator concentration distribution within the scintillator layer. The central region has a higher activator concentration (0.5-2.0 mass%) to improve sensitivity and light emission, while the peripheral regions have lower concentrations to reduce afterimage effects. This spatial variation in composition allows simultaneous optimization of both sensitivity and afterimage characteristics in different functional zones of the detector.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by precisely controlling the activator concentration within specific ranges (0.5-2.0 mass% in central region, 0.1-1.0 mass% in peripheral regions) and maintaining uniformity within ±15% in-plane and ±10% through-thickness. By optimizing these concentration parameters and their distributions, the patent achieves improved sensitivity while suppressing afterimage effects that occur with uniform high concentrations.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If the activator concentration distribution is not controlled, then the manufacturing process is simpler, but the scintillator layer characteristics degrade

Engineering Contradiction:
Improvemanufacturing processVSAvoidscintillator layer characteristics
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent establishes specific parameter ranges for activator concentration (0.5-2.0 mass% central, 0.1-1.0 mass% peripheral) and uniformity tolerances (±15% in-plane, ±10% through-thickness). These parameter specifications provide clear manufacturing targets that balance process feasibility with performance requirements, enabling controlled production of scintillator layers with optimized characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements local quality control by specifying different concentration requirements for different regions: higher concentrations (0.5-2.0 mass%) in the central imaging region where sensitivity is critical, and lower concentrations (0.1-1.0 mass%) in peripheral regions where afterimage control is prioritized. This regional differentiation maintains manufacturing simplicity while ensuring reliable scintillator performance.

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If the activator concentration is optimized for sensitivity, then the luminous efficiency improves, but the afterimage characteristics worsen

Engineering Contradiction:
Improveluminous efficiencyVSAvoidafterimage
Core Design Contradiction:
Use of energy by moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent resolves this energy efficiency versus afterimage contradiction by implementing local quality optimization. In the central region where diagnostic imaging occurs, higher activator concentrations (0.5-2.0 mass%) maximize luminous efficiency and light output. In peripheral regions, lower concentrations (0.1-1.0 mass%) minimize afterimage effects. This spatial optimization allows the system to achieve high energy efficiency where needed without suffering from peripheral afterimage degradation.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies parameter changes by establishing optimal activator concentration ranges that balance luminous efficiency and afterimage suppression. The central region parameters (0.5-2.0 mass%) are optimized for maximum light emission, while peripheral parameters (0.1-1.0 mass%) are optimized for afterimage control. The uniformity specifications (±15% in-plane, ±10% through-thickness) ensure these parameter variations produce the desired performance balance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized Tl concentration and distribution in the scintillator layer significantly reduce afterimages, enhance sensitivity, and maintain stable characteristics, improving the reliability and performance of the X-ray detector.

Implementation Method 1

a scintillator layer that contacts the photoelectric conversion substrate and converts the X-rays incident from the outside into light

Methodology Applied
Scientific EffectScintillation: Scintillation

Implementation Method 2

a photoelectric conversion substrate that converts light into an electrical signal

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Implementation Method 3

optimized through vacuum vapor deposition using multiple evaporation sources

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentEP3070500B1Radiation detector and method for manufacturing radiation detector
Publication Date: 2024.09.25 CANON ELECTRON TUBES & DEVICES CO LTD
  • EP3070500B1 patent drawingFigure 1~2
  • EP3070500B1 patent drawingFigure 3~4
  • EP3070500B1 patent drawingFigure 5~6

AI summary

According to an embodiment, a radiation detector comprises a photoelectric conversion substrate and a scintillator layer. The photoelectric conversion substrate converts light into an electrical signal. The scintillator layer contacts the photoelectric conversion substrate and converts radiation incident from the outside into light. The scintillator layer is a fluorescer of CsI containing TI as an activator. The CsI is a halide. The concentration of the activator inside the fluorescer is 1.6 mass% ±0.4 mass%. The concentration of the activator inside the fluorescer in an in-plane direction of the scintillator layer has the relationship of central portion > peripheral portion. The central portion is a central region of a formation region of the scintillator layer. The peripheral portion is an outer circumferential region of the formation region of the scintillator layer.