CTMP Pulp Dilution to Reduce Extractives Re-adsorption

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Solution Overview

Problem

Chemithermomechanical pulp (CTMP) typically contains high levels of wood extractives, which cause taste and odor issues in applications like food packaging, particularly due to the re-adsorption of extractives onto fibers during the dewatering process, making it difficult to achieve low extractives content.

Innovation Solution

A method involving a pulper to rapidly dilute the pulp to a consistency of 2-8 wt.% after refining, reducing residence time and preventing re-adsorption of extractives, combined with high-temperature steam treatment and bleaching steps to enhance extractives removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If the pulp is diluted slowly in the pulper (residence time >15 min), then the pulp achieves good homogeneous dispersion, but the extractives have time to re-adsorb to the fibers making them harder to remove

Engineering Contradiction:
Improvehomogeneous dispersion of pulpVSAvoidre-adsorption of extractives to fibers
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent applies the principle of rushing through the pulping process by reducing the residence time in the pulper to less than 15 minutes. This allows the pulp to be rapidly diluted and transferred to the dewatering stage, minimizing the time window during which extractives can re-adsorb to fibers while still achieving adequate homogeneous dispersion through intensive mixing during this compressed timeframe.

Inventive Principle:
Principle #21Skipping (Rushing through)

2Object-generated harmful factors

If the residence time in the pulper is reduced to less than 15 min, then the removal of extractives is improved, but the time required for homogeneous dilution is insufficient

Engineering Contradiction:
Improveremoval of extractivesVSAvoidtime for homogeneous dilution
Core Design Contradiction:
Object-generated harmful factorsVSLoss of time

Solution Approach 1:

The patent applies preliminary action by performing intensive mixing and homogeneous dilution of the pulp during the compressed residence time in the pulper before extraction. The system prepares the pulp slurry with adequate homogeneity through high-intensity mixing during the brief residence time, so that when extraction occurs, the pulp is already properly dispersed and ready for efficient extractive removal without requiring additional time.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If conventional CTMP production methods are used, then the process is simple and fast, but the extractives content remains high causing taste and odor issues

Engineering Contradiction:
Improveproduction speedVSAvoidextractives content
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies the extraction principle by introducing a dedicated extraction stage following the pulping process. During this stage, the diluted pulp undergoes extraction treatment (such as washing or chemical extraction) specifically targeted at removing extractives from the fiber structure. This separate extraction step effectively reduces extractives content to levels suitable for food packaging applications while maintaining the overall productivity of the CTMP production process.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces the content of extractives in CTMP, improving its suitability for food packaging applications by ensuring efficient removal and minimizing taste and odor issues.

Implementation Method 1

diluting the pulp in a pulper to obtain a diluted pulp, wherein the residence time in the pulper is less than 15 min

Methodology Applied
Scientific EffectDilution:

Implementation Method 2

By diluting the pulp in a pulper, the pulp may be homogeneously diluted within less than 15 min

Methodology Applied
Scientific EffectMixing:

Implementation Method 3

heating the impregnated chips with steam to obtain pre-treated chips

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

heating the impregnated chips with steam to obtain pre-treated chips

Methodology Applied
Scientific EffectSteam treatment:

Implementation Method 5

followed by a heat treatment to soften the wood

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 6

dewatering the diluted pulp

Methodology Applied
Scientific EffectDewatering:

Implementation Method 7

Diluting the pulp after refining may further help to disperse the extractives in the water phase and thereby facilitate their removal in a subsequent dewatering step

Methodology Applied
Scientific EffectSeparation:

Implementation Method 8

defibrating of the pre-treated chips to obtain a pulp

Methodology Applied
Scientific EffectDefibration:

Implementation Method 9

The treated wood chips are then subjected to defibration/refining

Methodology Applied
Scientific EffectMechanical force: Mechanical Force

Data Source

PatentEP4389965A1A method for producing CTMP having a low extractives content
Publication Date: 2024.06.26 BILLERUD AB
  • EP4389965A1 patent drawingFigure 1
  • EP4389965A1 patent drawingFigure 2~3
  • EP4389965A1 patent drawingFigure 4~5

AI summary

The present disclosure relates to a method for producing chemithermomechanical pulp, CTMP, comprising: a) providing wood chips comprising hardwood, softwood or a mixture thereof; b) impregnating the wood chips with an impregnation liquid to obtain impregnated chips; c) heating the impregnated chips with steam to obtain pre-treated chips; d) defibrating the pre-treated chips to obtain a pulp; e) diluting the pulp in a pulper, wherein the residence time in the pulper is less than 15 min; and f) dewatering the diluted pulp.