3D Printing Fusing Agent Color Control via CTO Nanoparticles

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Solution Overview

Problem

Current 3D printing techniques using Multi Jet Fusion (MJF) face challenges in achieving color variation while maintaining mechanical integrity, as fusing agents tend to produce strongly colored parts due to high absorption in the visible spectrum, limiting the range of colors that can be produced.

Innovation Solution

The use of a low tint fusing agent, such as stabilized cesium tungsten oxide (CTO) nanoparticles, which absorbs radiation in the near-infrared spectrum and is transparent in the visible spectrum, allowing for the production of white or lightly colored parts, and the combination of core and low tint fusing agents to achieve both mechanical integrity and color variation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional fusing agents with high visible spectrum absorption are used, then mechanical integrity is achieved, but color variation is limited and parts appear strongly colored

Engineering Contradiction:
Improvemechanical integrityVSAvoidcolor variation
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent segments the fusing agent into two distinct types: a core fusing agent containing carbon black for mechanical integrity, and a low-tint fusing agent for color control. These are applied in separate sequential steps, allowing independent optimization of each function without compromise

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different fusing agents to different regions of the build material layer. The core fusing agent is applied where mechanical strength is needed, while the low-tint fusing agent is applied where color control is prioritized, enabling spatial differentiation of material properties

Inventive Principle:
Principle #3Local quality

2Strength

If core fusing agent is applied to ensure mechanical strength, then part strength is improved, but the parts become strongly colored (black)

Engineering Contradiction:
Improvepart strengthVSAvoidunwanted strong coloration
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent extracts the color-generating function from the mechanical fusing function by separating carbon black (core fusing agent) from the low-tint fusing agent. This allows the harmful coloration effect to be removed while preserving the beneficial mechanical strengthening effect

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a composite approach by combining two different fusing agents with distinct properties: carbon black-based core fusing agent for strength, and low-tint fusing agent for color control. This composite strategy enables simultaneous achievement of mechanical integrity and aesthetic quality

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the creation of 3D parts with improved mechanical properties and a wider range of colors, including white and other colors beyond black, by selectively applying fusing agents to achieve desired color and strength profiles within the printed parts.

Implementation Method 1

The fusing agent is capable of absorbing radiation and converting the absorbed radiation to thermal energy, which in turn melts or sinters the build material that is in contact with the fusing agent

Methodology Applied
Scientific EffectRadiation absorption and thermal energy conversion: Absorption (EM radiation)

Implementation Method 2

a low tint fusing agent, such as stabilized cesium tungsten oxide (CTO) nanoparticles, which absorbs radiation in the near-infrared spectrum and is transparent in the visible spectrum

Methodology Applied
Scientific EffectSelective radiation absorption: Absorption (EM radiation)

Data Source

PatentEP3397455B1Three-dimensional (3D) printing
Publication Date: 2022.07.06 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • EP3397455B1 patent drawingFigure 1
  • EP3397455B1 patent drawingFigure 2
  • EP3397455B1 patent drawingFigure 3

AI summary

In an example of a three-dimensional printing method, a polymeric build material is applied. A fusing agent is selectively applied on at least a portion of the polymeric build material. The fusing agent includes cesium tungsten oxide nanoparticles, a zwitterionic stabilizer, and an aqueous vehicle. The polymeric build material is exposed to electromagnetic radiation to fuse the portion of the polymeric build material in contact with the fusing agent to form a layer.