Continuous Take-Off Pressure Control for Polymerization Reactors

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Solution Overview

Problem

The existing polyolefin production processes using multiple reactors in series often face issues with unstable slurry flow, leading to reactor clogging and fouling, which results in off-spec products and significant downtime, due to the 'salting out' of solids during slurry transfer between reactors.

Innovation Solution

The implementation of Continuous Take-Off (CTO) devices and optimized transfer line designs that modulate slurry flow and pressure control, allowing for higher solids concentration and reduced risk of fouling by maintaining stable slurry velocities and pressures, thereby preventing salting out and ensuring continuous operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If multiple reactors are used in series to produce multimodal polymers, then polymer product quality is improved, but slurry flow stability deteriorates causing clogging and fouling

Engineering Contradiction:
Improvepolymer product qualityVSAvoidslurry flow stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by independently controlling pressure and flow rate parameters in each reactor. By adjusting these parameters, the system maintains stable slurry flow and prevents salting out while producing polymers with different molecular weight distributions, thus improving product quality without compromising flow stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements feedback control by continuously monitoring slurry flow characteristics and reactor conditions. This feedback mechanism allows real-time adjustment of operating parameters to maintain stable slurry transfer and prevent clogging, ensuring both high product quality and reliable operation.

Inventive Principle:
Principle #23Feedback

2Productivity

If slurry transfer is performed between reactors, then polymer production continues, but reactor clogging occurs due to salting out of solids

Engineering Contradiction:
Improvepolymer production continuityVSAvoidreactor clogging
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent uses parameter changes by optimizing pressure differential and flow rate during slurry transfer. These parameter adjustments prevent solids from salting out and clogging the transfer line, enabling continuous polymer production without interruption.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent ensures continuity of useful action by maintaining continuous slurry flow from one reactor to another under controlled conditions. This continuous operation prevents polymer accumulation and clogging in transfer lines, allowing uninterrupted polymer production.

Inventive Principle:
Principle #20Continuity of useful action

3Productivity

If reactor clogging is prevented by optimizing slurry flow, then productivity increases, but device complexity increases due to additional control mechanisms

Engineering Contradiction:
Improvepolymer production efficiencyVSAvoidcontrol system complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies self-service by designing the reactor system to automatically regulate its own operation through inherent pressure differentials and flow dynamics. This reduces the need for complex external control mechanisms while maintaining high productivity and preventing clogging.

Inventive Principle:
Principle #25Self-service

Data Source

PatentEP2738184B2Continuous take off technique and pressure control of polymerization reactors
Publication Date: 2023.05.17 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • EP2738184B2 patent drawingFigure 1
  • EP2738184B2 patent drawingFigure 2
  • EP2738184B2 patent drawingFigure 3

AI summary

Techniques and systems for producing a polyolefin using reactors in series are described. Described embodiments include techniques and systems for polymerizing a monomer in a first polymerization reactor to form a first polyolefin, discharging a first slurry continuously from the first polymerization reactor to a second polymerization reactor, and discharging a second slurry continuously from the second polymerization reactor. Using continuous take-off devices disposed on either or both reactors, pressure control may be attained such that the rate of transfer between and withdrawal from both reactors are within a desired range.