Cu Alloy Powder Composition for Dense Low-Void Additive Manufacturing

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Solution Overview

Problem

Conventional Cu-based alloys are unsuitable for processes involving rapid melting and rapid solidification, such as additive manufacturing, thermal spraying, and laser coating, as they result in low-density shaped objects with voids and poor electroconductivity.

Innovation Solution

A Cu-based alloy powder with specific compositions and structures, including elements like Cr, Fe, Ni, Zr, and Nb, optimized for rapid melting and solidification processes, which suppresses laser reflectance and heat loss, ensuring high-density and high-electroconductivity shaped objects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional Cu-based alloys are used for rapid melting and rapid solidification processes, then the material can be processed, but the resulting shaped objects have low density and contain voids

Engineering Contradiction:
Improvedensity of shaped objectVSAvoidquality of shaped object (void formation)
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition parameters of the Cu-based alloy (adding specific amounts of Cr, Fe, Ni, Zr, and Nb elements within defined ranges) and physical parameters (particle size distribution D50/TD ratio and sphericity). These parameter optimizations enable the alloy to achieve high density and eliminate voids during rapid melting and solidification processes.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional Cu-based alloys are used for rapid melting and rapid solidification, then processing can proceed, but electroconductivity deteriorates

Engineering Contradiction:
ImproveelectroconductivityVSAvoidquality of shaped object
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes composition parameters by limiting the content of electroconductivity-deteriorating elements (Si ≤ 0.20%, P ≤ 0.10%, S ≤ 0.10%) while incorporating beneficial alloying elements (Cr, Fe, Ni, Zr, Nb) within specific ranges. This parameter control achieves superior electroconductivity while maintaining high manufacturing quality in the shaped objects.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If Cu-based alloy powder is used for additive manufacturing, then three-dimensional shaped objects can be produced, but high density is difficult to achieve

Engineering Contradiction:
Improvedensity of shaped objectVSAvoiddifficulty of obtaining high-density object
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent changes the powder material parameters (composition, particle size distribution with D50/TD ratio of 0.2-20×10^-5 m^4/Mg, and sphericity of 0.80-0.95) to enable high-density shaped objects to be obtained through standard additive manufacturing processes without requiring difficult or complex manufacturing adjustments.

Inventive Principle:
Principle #35Parameter changes

4Use of energy by moving object

If conventional Cu-based alloys undergo rapid melting and rapid solidification, then shaped objects are produced, but laser reflectance causes heat loss

Engineering Contradiction:
Improveheat absorption efficiencyVSAvoidheat loss due to laser reflectance
Core Design Contradiction:
Use of energy by moving objectVSLoss of energy

Solution Approach 1:

The patent modifies the optical parameters of the Cu-based alloy by incorporating alloying elements (Cr, Fe, Ni, Zr, Nb) that alter the material's laser reflectance characteristics. This parameter change improves heat absorption efficiency and reduces energy loss during laser-based rapid melting and solidification processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized Cu-based alloy powder achieves high-density and low-void shaped objects with superior electroconductivity, suitable for complex three-dimensional additive manufacturing and other rapid solidification processes.

Implementation Method 1

suppresses laser reflectance and heat loss

Methodology Applied
Scientific EffectLaser reflectance suppression: Absorption (EM radiation)

Implementation Method 2

a metal material is melted rapidly and quenched to solidify

Methodology Applied
Scientific EffectRapid melting and rapid solidification: Melting

Implementation Method 3

Cu-based alloys are suitable for such applications [high conductivity required]

Methodology Applied
Scientific EffectHeat conduction: Conduction (thermal)

Data Source

PatentUS11987870B2Cu-based alloy powder
Publication Date: 2024.05.21 SANYO SPECIAL STEEL CO LTD

AI summary

Provided is a Cu-based alloy powder that is suitable for a process involving rapid melting and rapid solidification and that can provide a shaped object superior in characteristics. The powder is composed of a Cu-based alloy, which contains an element M being one or more elements selected from Cr, Fe, Ni, Zr, and Nb: 0.1% by mass or more and 10.0% by mass or less, Si: more than 0% by mass and 0.20% by mass or less, P: more than 0% by mass and 0.10% by mass or less, and S: more than 0% by mass and 0.10% by mass or less, the balance being Cu and inevitable impurities. This powder has a ratio (D50/TD) of the average particle diameter D50 (μm) thereof to the tap density TD (Mg/m3) is 0.2×10−5·m4/Mg or more and 20×10−5·m4/Mg or less, and has a sphericity of 0.80 or more and 0.95 or less.