Cu Alloy Bonding Wire Microstructure for Loop Straightness

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Solution Overview

Problem

Bare Cu wires used in high-density semiconductor devices face challenges in maintaining loop straightness, resisting deformation during resin sealing, and ensuring long-term service life, particularly in high-temperature storage tests, due to issues with crystal grain orientation and deformation under ultrasonic bonding processes.

Innovation Solution

A Cu alloy bonding wire with specific crystal orientation abundance ratios and additional elements like Ni, Pd, Pt, P, In, Ga, Ge, and Ag, optimized to improve loop straightness, reduce neck portion damage, and enhance ball bond area life, by controlling crystal orientations and grain sizes to minimize plastic anisotropy and promote isotropic deformation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high ultrasonic wave output is used to obtain bonding strength in wedge bond areas, then bonding strength is improved, but loop straightness deteriorates due to bending caused by ultrasonic waves

Engineering Contradiction:
Improvebonding strengthVSAvoidloop straightness
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The patent applies parameter changes by precisely controlling the crystal grain size (5 μm or less) and crystal orientation (〈100〉direction alignment) of the Cu wire. This microstructural parameter control enables the wire to achieve adequate bonding strength through controlled deformation during the scrub process, rather than relying on high ultrasonic wave output, thereby preventing loop bending while maintaining bonding strength.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the wire diameter is reduced to 25 μm or less to achieve high packaging density, then packaging density is improved, but loop straightness deteriorates due to reduced loop portion strength

Engineering Contradiction:
Improvepackaging densityVSAvoidloop straightness
Core Design Contradiction:
ProductivityVSShape

Solution Approach 1:

The patent applies parameter changes by controlling the crystal grain size to 5 μm or less and ensuring crystal orientation with 〈100〉direction alignment in the wire longitudinal direction. This microstructural parameter control compensates for the reduced cross-sectional area of thin wires (25 μm or less), providing sufficient strength to maintain loop straightness while enabling high packaging density through smaller wire diameter.

Inventive Principle:
Principle #35Parameter changes

3Shape

If the aspect ratio of crystal grains on the skin layer surface is increased to 3 or more to improve loop straightness, then loop straightness is improved, but resistance to deformation during resin sealing deteriorates

Engineering Contradiction:
Improveloop straightnessVSAvoiddeformation resistance
Core Design Contradiction:
ShapeVSStrength

Solution Approach 1:

The patent applies parameter changes by controlling both crystal grain size (5 μm or less) and crystal orientation (〈100〉direction alignment). This dual parameter control achieves loop straightness through isotropic deformation characteristics while maintaining adequate deformation resistance during resin sealing, overcoming the limitation of aspect ratio-based solutions that compromise strength.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If bare Cu wires are used to reduce cost, then manufacturing cost is reduced, but oxidation resistance and bondability deteriorate

Engineering Contradiction:
Improvemanufacturing costVSAvoidoxidation resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies the inert atmosphere principle by specifying that the Cu wire surface is covered with an organic substance film formed in an inert or reducing atmosphere. This protective film prevents oxidation of the Cu wire while maintaining the cost advantage of using bare Cu wires instead of coated wires, thereby improving oxidation resistance without sacrificing manufacturing cost benefits.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively maintains high loop straightness, reduces neck portion damage, and extends ball bond area life to meet the performance requirements of high-density semiconductor devices, ensuring reliable operation under severe conditions.

Implementation Method 1

In the wedge bonding of bare Cu wires, an operation called a scrub, which vibrates a stage at a low frequency, is often used together while the wire is pressed by a capillary. The scrub promotes the deformation of the wire and is effective for improving the bonding strength of the wedge bond areas.

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Implementation Method 2

A bonding process for a bonding wire involves heat-melting a wire tip by arc heat input, forming a ball (FAB: Free Air Ball) by surface tension

Methodology Applied
Scientific EffectArc heating: Electric Arc

Implementation Method 3

heat-melting a wire tip by arc heat input, forming a ball (FAB: Free Air Ball) by surface tension

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 4

pressure-bonding a ball portion (hereinafter referred to as ball bonding) to an electrode of a semiconductor element heated in a range of 150 to 300°C

Methodology Applied
Scientific EffectThermal heating: Heating

Data Source

PatentEP3745450B1Cu alloy bonding wire for semiconductor device
Publication Date: 2024.08.28 NIPPON STEEL CHEM & MATERIAL CO LTD
  • EP3745450B1 patent drawingFigure 1
  • EP3745450B1 patent drawingFigure 2A~2B
  • EP3745450B1 patent drawingFigure 3

AI summary

It is an object to provide a Cu alloy bonding wire for a semiconductor device that can satisfy required performance in high-density LSI applications. In the Cu alloy bonding wire for a semiconductor device according to the present invention, each of abundance ratios of crystal orientations <100>, <110> and <111> having an angular difference of 15 degrees or less from a direction perpendicular to one plane including a wire center axis out of crystal orientations on a wire surface is 3% or more and less than 27% in average area percentage.