Cu-Ni-Si Copper Alloy Sheet for Smooth Precision Etching

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Solution Overview

Problem

Current Cu-Ni-Si based copper alloy sheet materials for high-precision lead frames face challenges in achieving high strength, surface smoothness, and dimensional accuracy, particularly in precision etching and pin formation with narrow widths.

Innovation Solution

The solution involves optimizing the Cu-Ni-Si based copper alloy by controlling the KAM value through appropriate cold rolling and annealing processes, using a large-diameter work roll for finish cold rolling, and strict tension and cooling rate control to enhance surface smoothness and flatness, while maintaining high strength and electrical conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If the strength of the material is increased to achieve narrower pin width, then the pin width can be reduced, but the surface smoothness of the etched surface deteriorates

Engineering Contradiction:
Improvepin widthVSAvoidsurface smoothness of etched surface
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition parameters (Ni: 1.5-3.6%, Si: 0.3-1.0%, Co: 0.01-2.0%) and processing parameters (cold rolling reduction ratio: 5-20%, annealing temperature: 200-400°C, annealing time: 1-10 hours) to achieve both high strength and good surface smoothness simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs dynamics by implementing a multi-stage processing sequence that dynamically adjusts the material properties: first cold rolling to introduce strain and refine grain structure, then annealing to relieve stress and restore ductility, creating an optimal balance between strength and surface quality for precision etching

Inventive Principle:
Principle #15Dynamics

2Length of moving object

If the strength of the material is increased to achieve narrower pin width, then the pin width can be reduced, but the dimensional accuracy of the lead frame deteriorates

Engineering Contradiction:
Improvepin widthVSAvoiddimensional accuracy
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by performing cold rolling and annealing treatments before the precision etching process. These preliminary treatments pre-establish the optimal microstructure and mechanical properties, ensuring that the material can maintain dimensional accuracy during subsequent high-precision manufacturing operations

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent controls composition parameters (Ni: 1.5-3.6%, Si: 0.3-1.0%, Co: 0.01-2.0%) and processing parameters (cold rolling reduction ratio: 5-20%, annealing temperature: 200-400°C, annealing time: 1-10 hours) to achieve both high strength and good surface smoothness simultaneously

Inventive Principle:
Principle #35Parameter changes

3Strength

If cold rolling and annealing processes are applied to increase strength, then the strength improves, but the surface smoothness and flatness deteriorate

Engineering Contradiction:
Improve0.2% offset yield strengthVSAvoidsurface smoothness and flatness
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent optimizes the cold rolling reduction ratio to a specific range (5-20%) and controls annealing parameters (temperature: 200-400°C, time: 1-10 hours) to achieve the right balance between strength enhancement and surface quality preservation. The controlled parameters ensure sufficient grain refinement for strength while minimizing surface degradation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a dynamic processing sequence where cold rolling is followed by annealing. The cold rolling stage introduces strain and refines the grain structure to increase strength, while the subsequent annealing stage relieves internal stress and restores surface smoothness, creating an optimal balance between strength and surface quality

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a Cu-Ni-Si based copper alloy sheet material with improved surface smoothness, high strength, and excellent dimensional accuracy, making it suitable for high-precision components like lead frames with narrow pins.

Implementation Method 1

an appropriate strain by cold rolling is applied between the solution treatment and the aging treatment

Methodology Applied
Scientific EffectCold rolling: Cold-forming

Implementation Method 2

solution treatment water quenching aging (525 °C, 3 hours)

Methodology Applied
Scientific EffectSolution treatment: Heat Treatment

Implementation Method 3

aging (525 °C, 3 hours) cold rolling (90%) aging (325 - 400 °C, 17- 20 hours)

Methodology Applied
Scientific EffectAging: Annealing

Implementation Method 4

in the final low temperature annealing, the temperature rising rate is controlled, so as not to become excessively large

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 5

the work roll for the finish cold rolling performed after the aging treatment has a large diameter, and the single rolling reduction ratio in the final pass is restricted

Methodology Applied
Scientific EffectCold rolling: Cold-forming

Implementation Method 6

in the shape correction with a tension leveler, the elongation rate is strictly controlled, so as to prevent excessive work from being applied

Methodology Applied
Scientific EffectPlastic deformation: Plasticity

Implementation Method 7

a copper alloy which includes, by mass, 1.5 to 3.6% Ni, 0.3 to 1.0% Si, and the remainder consisting of copper... the copper alloy inter alia has a KAM value of 1.0 to 3.0

Methodology Applied
Scientific EffectPrecipitation hardening: Precipitation Hardening

Data Source

PatentEP3438300B1Cu-ni-si copper alloy sheet and manufacturing method
Publication Date: 2021.09.08 DOWA METALTECH CO LTD
  • EP3438300B1 patent drawing
  • EP3438300B1 patent drawing
  • EP3438300B1 patent drawing

AI summary

[Problem] A high strength Cu-Ni-Si based copper alloy sheet material excellent in surface smoothness of the etched surface is provided. [Solution] A copper alloy sheet material having: a composition containing, in terms of percentage by mass, from 1.0 to 4.5% of Ni, from 0.1 to 1.2% of Si, from 0 to 0.3% of Mg, from 0 to 0.2% of Cr, from 0 to 2.0% of Co, from 0 to 0.1% of P, from 0 to 0.05% of B, from 0 to 0.2% of Mn, from 0 to 0.5% of Sn, from 0 to 0.5% of Ti, from 0 to 0.2% of Zr, from 0 to 0.2% of Al, from 0 to 0.3% of Fe, from 0 to 1.0% of Zn, the balance of Cu, and unavoidable impurities; having a number density of coarse secondary phase particles having a major diameter of 1.0 µm or more of 4.0 × 103 per square millimeter or less, on an observation surface in parallel to a sheet surface; and having a KAM value measured with a step size of 0.5 µm of more than 3.00, within a crystal grain assuming that a boundary with a crystal orientation difference of 15º or more by EBSD is a crystal grain boundary.